Ethanone, 1-(2,6-dihydroxycyclohexyl)-, (2alpha,6alpha)- (9CI)

Base Information

• Chemical Name: Ethanone, 1-(2,6-dihydroxycyclohexyl)-, (2alpha,6alpha)- (9CI)
• CAS No.: 119458-58-1
• Molecular Formula: C₈H₁₄O₃
• Molecular Weight: 158.197
• Mol file: 119458-58-1.mol

Synonyms:Ethanone, 1-(2,6-dihydroxycyclohexyl)-, (2alpha,6alpha)- (9CI)

Chemical Property of Ethanone, 1-(2,6-dihydroxycyclohexyl)-, (2alpha,6alpha)- (9CI)

Chemical Property:

Purity/Quality:

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Technology Process of Ethanone, 1-(2,6-dihydroxycyclohexyl)-, (2alpha,6alpha)- (9CI)

There total 5 articles about Ethanone, 1-(2,6-dihydroxycyclohexyl)-, (2alpha,6alpha)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

(3aS,4S,7aR)-3-Methyl-3a,4,5,6,7,7a-hexahydro-benzo[d]isoxazol-4-ol (67431-05-4,75282-46-1) → 1-(6-hydroxy-1-cyclohexnyl)(phenyl)-1-ethanone (67431-04-3) + 1-((1S,2R,6S)-2,6-Dihydroxy-cyclohexyl)-ethanone (70433-50-0,119458-58-1,119565-97-8)

Guidance literature:

With hydrogenchloride; nickel; In methanol; water; at 0 ℃;

DOI:10.1007/BF00633180

Reference yield: 65.0%

(3aS,4S,7aR)-3-Methyl-3a,4,5,6,7,7a-hexahydro-benzo[d]isoxazol-4-ol (67431-05-4,75282-46-1) → 1-((2R,6R)-2,6-Dihydroxy-cyclohexyl)-ethanone (70433-50-0,119458-58-1,119565-97-8) + 1-((1S,2R,6S)-2,6-Dihydroxy-cyclohexyl)-ethanone (70433-50-0,119458-58-1,119565-97-8)

Guidance literature:

With hydrogen; boric acid; nickel; In methanol; water; for 3h;

DOI:10.1007/BF00633180

Reference yield: 65.0%

(3aS,4S,7aR)-3-Methyl-3a,4,5,6,7,7a-hexahydro-benzo[d]isoxazol-4-ol (67431-05-4,75282-46-1) → 1-((2R,6R)-2,6-Dihydroxy-cyclohexyl)-ethanone (70433-50-0,119458-58-1,119565-97-8) + 1-((1S,2R,6S)-2,6-Dihydroxy-cyclohexyl)-ethanone (70433-50-0,119458-58-1,119565-97-8)

Guidance literature:

With hydrogen; boric acid; nickel; In methanol; water; for 3h;

DOI:10.1007/BF00633180

upstream raw materials:

(3aS,4S,7aR)-3-Methyl-3a,4,5,6,7,7a-hexahydro-benzo[d]isoxazol-4-ol

rac-(3aR,7aR)-3-methyl-5,6,7,7a-tetrahydro-3aH-benzo[d]isoxazol-4-one