1-O-<15-(3-iodophenyl)pentadecanoyl>-3-O-trityl-1,3-dihydroxy-2-propanone

Base Information

Chemical Name:1-O-<15-(3-iodophenyl)pentadecanoyl>-3-O-trityl-1,3-dihydroxy-2-propanone
CAS No.:121269-74-7
Molecular Formula:C₄₃H₅₁IO₄
Molecular Weight:758.78
Hs Code.:

Synonyms:1-O-<15-(3-iodophenyl)pentadecanoyl>-3-O-trityl-1,3-dihydroxy-2-propanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-O-<15-(3-iodophenyl)pentadecanoyl>-3-O-trityl-1,3-dihydroxy-2-propanone

Chemical Property:

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Technology Process of 1-O-<15-(3-iodophenyl)pentadecanoyl>-3-O-trityl-1,3-dihydroxy-2-propanone

There total 14 articles about 1-O-<15-(3-iodophenyl)pentadecanoyl>-3-O-trityl-1,3-dihydroxy-2-propanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 121269-70-3
15-(3-iodophenyl)pentadecanoic acid

: 121269-73-6
1-hydroxy-3-(triphenylmethoxy)propan-2-one

: 121269-74-7
1-O-<15-(3-iodophenyl)pentadecanoyl>-3-O-trityl-1,3-dihydroxy-2-propanone

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; Ambient temperature;
DOI:10.1021/jm00129a014

Reference yield:

: 947-05-7
oxacyclotridecan-2-one

: 121269-74-7
1-O-<15-(3-iodophenyl)pentadecanoyl>-3-O-trityl-1,3-dihydroxy-2-propanone

Guidance literature:: Multi-step reaction with 7 steps

1: H₂SO₄ / 6 h / Heating

2: 68 percent / pyridinium chlorochromate (PCC) / CH₂Cl₂ / 2 h / Ambient temperature

3: 48 percent / KOt-Bu / CH₂Cl₂ / 3 h / Ambient temperature

4: 91 percent / H₂ / 5percent Pd/C / ethyl acetate / 4 h

5: 1) NaNO₂, HCl, 2) KI, I₂ / glacial acetic acid, H₂O, 1) 45 min., 2) 2.1) < 10 deg C, 2.5 h, 2.2) RT, overnight

6: 61 percent / KOH / methanol

7: 70 percent / DMAP, DCC / CH₂Cl₂ / Ambient temperature

With hydrogenchloride; dmap; potassium hydroxide; sulfuric acid; potassium tert-butylate; hydrogen; iodine; dicyclohexyl-carbodiimide; pyridinium chlorochromate; potassium iodide; sodium nitrite; palladium on activated charcoal; In methanol; dichloromethane; ethyl acetate;
DOI:10.1021/jm00129a014

Reference yield:

: 2009-59-8
methyl 11-formylundecanoate

: 121269-74-7
1-O-<15-(3-iodophenyl)pentadecanoyl>-3-O-trityl-1,3-dihydroxy-2-propanone

Guidance literature:: Multi-step reaction with 5 steps

1: 48 percent / KOt-Bu / CH₂Cl₂ / 3 h / Ambient temperature

2: 91 percent / H₂ / 5percent Pd/C / ethyl acetate / 4 h

3: 1) NaNO₂, HCl, 2) KI, I₂ / glacial acetic acid, H₂O, 1) 45 min., 2) 2.1) < 10 deg C, 2.5 h, 2.2) RT, overnight

4: 61 percent / KOH / methanol

5: 70 percent / DMAP, DCC / CH₂Cl₂ / Ambient temperature

With hydrogenchloride; dmap; potassium hydroxide; potassium tert-butylate; hydrogen; iodine; dicyclohexyl-carbodiimide; potassium iodide; sodium nitrite; palladium on activated charcoal; In methanol; dichloromethane; ethyl acetate;
DOI:10.1021/jm00129a014