Methyl 6-oxabicyclo[3.1.0]hexane-1-carboxylate

Base Information

Chemical Name:Methyl 6-oxabicyclo[3.1.0]hexane-1-carboxylate
CAS No.:119245-13-5
Molecular Formula:C₇H₁₀O₃
Molecular Weight:142.155
Hs Code.:2932990090
DSSTox Substance ID:DTXSID60558794
Mol file:119245-13-5.mol

Synonyms:119245-13-5;methyl 6-oxabicyclo[3.1.0]hexane-1-carboxylate;6-Oxabicyclo[3.1.0]hexane-1-carboxylicacid,methylester(9CI);SCHEMBL3623192;DTXSID60558794;SZAQFDMOPZOEBX-UHFFFAOYSA-N;6-Oxabicyclo[3.1.0]hexane-1-carboxylic acid, methyl ester

Suppliers and Price of Methyl 6-oxabicyclo[3.1.0]hexane-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Apolloscientific
Methyl6-oxabicyclo[3.1.0]hexane-3-carboxylate 95%
1g
$ 275.00

Total 2 raw suppliers

Chemical Property of Methyl 6-oxabicyclo[3.1.0]hexane-1-carboxylate

Chemical Property:

PSA：38.83000
LogP:0.48090
XLogP3:0.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:142.062994177
Heavy Atom Count:10
Complexity:178

Purity/Quality:

99% ^*data from raw suppliers

Methyl6-oxabicyclo[3.1.0]hexane-3-carboxylate 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C12CCCC1O2

Technology Process of Methyl 6-oxabicyclo[3.1.0]hexane-1-carboxylate

There total 3 articles about Methyl 6-oxabicyclo[3.1.0]hexane-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 25662-28-6
1-(carboxymethoxy)cyclopentadiene

: 119245-13-5
(+/-)-methyl 6-oxabicyclo<3.1.0>hexane-1-carboxylate

Guidance literature:: With 6,6'-di-tert-butyl-4,4'-thiodi-o-cresol; 3-chloro-benzenecarboperoxoic acid; In benzene; at 80 ℃; for 16h;
DOI:10.1002/recl.19921110101

Reference yield: 24.0%

: 25662-28-6
1-(carboxymethoxy)cyclopentadiene

: 108384-35-6
methyl 3-oxocyclopent-1-enecarboxylate

: 119245-13-5
(+/-)-methyl 6-oxabicyclo<3.1.0>hexane-1-carboxylate

Guidance literature:: With chromium(VI) oxide; acetic anhydride; acetic acid; In dichloromethane; at 11 - 14 ℃;
DOI:10.1021/jo00269a012

Reference yield:

: 4630-80-2
methyl cyclopentane carboxylate

: 119245-13-5
(+/-)-methyl 6-oxabicyclo<3.1.0>hexane-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) lithium diisopropylamide, 2) benzeneselenyl chloride, 40percent H₂O₂, AcOH / 1) THF, 0 deg C, 4 h, 2) THF, water, r.t., overnight

2: 65 percent / 80percent 3-chloroperbenzoic acid, bis(3-tert-butyl-4-hydroxy-5-methylphenyl)sulfide / benzene / 16 h / 80 °C

With Phenylselenyl chloride; 6,6'-di-tert-butyl-4,4'-thiodi-o-cresol; dihydrogen peroxide; acetic acid; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In benzene;
DOI:10.1002/recl.19921110101