phenyl 2,3,-di-O-benzoyl-4-O-benzyl-1-thio-β-D-glucopyranosyduronic acid

Base Information

Chemical Name:phenyl 2,3,-di-O-benzoyl-4-O-benzyl-1-thio-β-D-glucopyranosyduronic acid
CAS No.:1287768-27-7
Molecular Formula:C₃₃H₂₈O₈S
Molecular Weight:584.647
Hs Code.:

Synonyms:phenyl 2,3,-di-O-benzoyl-4-O-benzyl-1-thio-β-D-glucopyranosyduronic acid

Suppliers and Price of phenyl 2,3,-di-O-benzoyl-4-O-benzyl-1-thio-β-D-glucopyranosyduronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl 2,3,-di-O-benzoyl-4-O-benzyl-1-thio-β-D-glucopyranosyduronic acid

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl 2,3,-di-O-benzoyl-4-O-benzyl-1-thio-β-D-glucopyranosyduronic acid

There total 4 articles about phenyl 2,3,-di-O-benzoyl-4-O-benzyl-1-thio-β-D-glucopyranosyduronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: phenyl 2,3,-di-O-benzoyl-4-O-benzyl-1-thio-β-D-glucopyranoside

: 1287768-27-7
phenyl 2,3,-di-O-benzoyl-4-O-benzyl-1-thio-β-D-glucopyranosyduronic acid

Guidance literature:: With 1-chloro-1λ³-benzo[d][1,2]iodaoxol-3(1H)-one; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; In dichloromethane; water; at 20 ℃; for 3.5h;
DOI:10.1016/j.tetlet.2018.05.021

Reference yield:

: 71676-30-7,87508-18-7,138922-03-9,87508-17-6
(2R,4aR,6S,7R,8R,8aS)-2-Phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

: 1287768-27-7
phenyl 2,3,-di-O-benzoyl-4-O-benzyl-1-thio-β-D-glucopyranosyduronic acid

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / 0 - 20 °C

2: triethylsilane; phenylborondichloride / dichloromethane / 0.5 h / -78 - 20 °C / Molecular sieve

3: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 20 °C

With pyridine; triethylsilane; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; phenylborondichloride; In dichloromethane; water;
DOI:10.1021/jo200076z

Reference yield:

: 98-88-4
benzoyl chloride

: 1287768-27-7
phenyl 2,3,-di-O-benzoyl-4-O-benzyl-1-thio-β-D-glucopyranosyduronic acid

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / 0 - 20 °C

2: triethylsilane; phenylborondichloride / dichloromethane / 0.5 h / -78 - 20 °C / Molecular sieve

3: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 20 °C

With pyridine; triethylsilane; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; phenylborondichloride; In dichloromethane; water;
DOI:10.1021/jo200076z