(2E,6E)-9-cyclohexyl-3,7-dimethyl-1-tetrahydro-2-pyranyloxy-2,6-nonadien-1-ol

Base Information

Chemical Name:(2E,6E)-9-cyclohexyl-3,7-dimethyl-1-tetrahydro-2-pyranyloxy-2,6-nonadien-1-ol
CAS No.:502763-39-5
Molecular Formula:C₂₂H₃₈O₂
Molecular Weight:334.543
Hs Code.:

Synonyms:(2E,6E)-9-cyclohexyl-3,7-dimethyl-1-tetrahydro-2-pyranyloxy-2,6-nonadien-1-ol

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Chemical Property of (2E,6E)-9-cyclohexyl-3,7-dimethyl-1-tetrahydro-2-pyranyloxy-2,6-nonadien-1-ol

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Technology Process of (2E,6E)-9-cyclohexyl-3,7-dimethyl-1-tetrahydro-2-pyranyloxy-2,6-nonadien-1-ol

There total 4 articles about (2E,6E)-9-cyclohexyl-3,7-dimethyl-1-tetrahydro-2-pyranyloxy-2,6-nonadien-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 7331-99-9
((cyclohexylmethyl)sulfonyl)benzene

: 502763-31-7
(2E,6E)-2,6-dimethyl-8-(tetrahydro-2H-pyran-2-yloxy)octa-2,6-dienyl-4-methylbenzenesulfonate

: 502763-39-5
(2E,6E)-9-cyclohexyl-3,7-dimethyl-1-tetrahydro-2-pyranyloxy-2,6-nonadien-1-ol

Guidance literature:: ((cyclohexylmethyl)sulfonyl)benzene; With n-butyllithium; In tetrahydrofuran; at 0 ℃; for 0.5h;

(2E,6E)-2,6-dimethyl-8-(tetrahydro-2H-pyran-2-yloxy)octa-2,6-dienyl-4-methylbenzenesulfonate; With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; In tetrahydrofuran; at 0 - 20 ℃; for 20h;

With disodium hydrogenphosphate; sodium amalgam; In methanol; at 20 ℃; for 2h;
DOI:10.1016/S0040-4020(02)01455-2

Reference yield:

: 66408-80-8,70238-39-0,80444-67-3,143590-48-1,38290-53-8
(2E,6E)-2,6-dimethyl-8-((tetrahydro-2H-pyran-2-yl)oxy)octa-2,6-dien-1-ol

: 502763-39-5
(2E,6E)-9-cyclohexyl-3,7-dimethyl-1-tetrahydro-2-pyranyloxy-2,6-nonadien-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: 100 percent / (C₂H₅)3N; trimethylammonium hydrochloride / toluene / 2 h

2.1: n-C₄H₉Li / tetrahydrofuran / 0.5 h / 0 °C

2.2: 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidone / tetrahydrofuran / 20 h / 0 - 20 °C

2.3: 50 percent / Na-Hg; Na₂HPO₄ / methanol / 2 h / 20 °C

With n-butyllithium; trimethylamine hydrochloride; triethylamine; In tetrahydrofuran; toluene;
DOI:10.1016/S0040-4020(02)01455-2

Reference yield:

: 36293-56-8
(cyclohexylmethyl)(phenyl)sulfide

: 502763-39-5
(2E,6E)-9-cyclohexyl-3,7-dimethyl-1-tetrahydro-2-pyranyloxy-2,6-nonadien-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: 89 percent / Oxone (R) / methanol; H₂O / 19 h / 20 °C

2.1: n-C₄H₉Li / tetrahydrofuran / 0.5 h / 0 °C

2.2: 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidone / tetrahydrofuran / 20 h / 0 - 20 °C

2.3: 50 percent / Na-Hg; Na₂HPO₄ / methanol / 2 h / 20 °C

With Oxone; n-butyllithium; In tetrahydrofuran; methanol; water;
DOI:10.1016/S0040-4020(02)01455-2