2-(trimethylsilyl)ethyl 6-O-trityl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Base Information

Chemical Name:2-(trimethylsilyl)ethyl 6-O-trityl-2-deoxy-2-phthalimido-β-D-glucopyranoside
CAS No.:457931-07-6
Molecular Formula:C₃₈H₄₁NO₇Si
Molecular Weight:651.832
Hs Code.:

Synonyms:2-(trimethylsilyl)ethyl 6-O-trityl-2-deoxy-2-phthalimido-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(trimethylsilyl)ethyl 6-O-trityl-2-deoxy-2-phthalimido-β-D-glucopyranoside

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Technology Process of 2-(trimethylsilyl)ethyl 6-O-trityl-2-deoxy-2-phthalimido-β-D-glucopyranoside

There total 1 articles about 2-(trimethylsilyl)ethyl 6-O-trityl-2-deoxy-2-phthalimido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 76-83-5
trityl chloride

: 117252-99-0
2-(trimethylsilyl)ethyl 2-deoxy-2-phthalimido-β-D-glucopyranoside

: 457931-07-6
2-(trimethylsilyl)ethyl 6-O-trityl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: With pyridine; at 50 ℃; for 4h;
DOI:10.1248/cpb.50.600

Reference yield: 88.0%

: 100-39-0
benzyl bromide

: 457931-07-6
2-(trimethylsilyl)ethyl 6-O-trityl-2-deoxy-2-phthalimido-β-D-glucopyranoside

: 457931-08-7
2-(trimethylsilyl)ethyl 3,4-di-O-benzyl-6-O-trityl-2-deoxy-2-phthalimido-β-D-glucopyranoside

Guidance literature:: With tetrabutylammomium bromide; sodium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 2h;
DOI:10.1248/cpb.50.600

Reference yield:

: 457931-07-6
2-(trimethylsilyl)ethyl 6-O-trityl-2-deoxy-2-phthalimido-β-D-glucopyranoside

: 2,2-Dimethyl-propionic acid (2R,3S,4R,5R,6R)-3,4-bis-benzyloxy-5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-6-hydroxy-tetrahydro-pyran-2-ylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 88 percent / tetrabutyl ammonium bromide; NaH / dimethylformamide / 2 h / 0 °C

2: 100 percent / p-toluene sulfonic acid / CH₂Cl₂; methanol / 20 h / 20 °C

3: 100 percent / pyridine / 5 h / 0 °C

4: trifluoroacetic acid / CH₂Cl₂ / 1 h / 20 °C

With pyridine; tetrabutylammomium bromide; sodium hydride; toluene-4-sulfonic acid; trifluoroacetic acid; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1248/cpb.50.600