(S)-7-methylene-3-(2-nitrophenoxy)-1-(2-nitrobenzenesulfonyl)-1,5-diazecane

Base Information

Chemical Name:(S)-7-methylene-3-(2-nitrophenoxy)-1-(2-nitrobenzenesulfonyl)-1,5-diazecane
CAS No.:1609184-22-6
Molecular Formula:C₂₁H₂₄N₄O₇S
Molecular Weight:476.51
Hs Code.:

Synonyms:(S)-7-methylene-3-(2-nitrophenoxy)-1-(2-nitrobenzenesulfonyl)-1,5-diazecane

Suppliers and Price of (S)-7-methylene-3-(2-nitrophenoxy)-1-(2-nitrobenzenesulfonyl)-1,5-diazecane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (S)-7-methylene-3-(2-nitrophenoxy)-1-(2-nitrobenzenesulfonyl)-1,5-diazecane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (S)-7-methylene-3-(2-nitrophenoxy)-1-(2-nitrobenzenesulfonyl)-1,5-diazecane

There total 13 articles about (S)-7-methylene-3-(2-nitrophenoxy)-1-(2-nitrobenzenesulfonyl)-1,5-diazecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 1609184-08-8
(R)-7-methylene-1,5-bis((2-nitrobenzene)sulfonyl)-1,5-diazecan-3-ol

: 1609184-22-6
(S)-7-methylene-3-(2-nitrophenoxy)-1-(2-nitrobenzenesulfonyl)-1,5-diazecane

Guidance literature:: With caesium carbonate; In acetonitrile; at 80 ℃; for 4h; Solvent; Inert atmosphere;
DOI:10.1021/ol5010033

Reference yield: 8.0%

: 1609184-07-7
(S)-N-glycidyl-N-(2-methylene-5-(2-nitrobenzenesulfonamido)pentyl)-2-nitrobenzenesulfonamide

: 1609184-08-8
(R)-7-methylene-1,5-bis((2-nitrobenzene)sulfonyl)-1,5-diazecan-3-ol

: 1609184-22-6
(S)-7-methylene-3-(2-nitrophenoxy)-1-(2-nitrobenzenesulfonyl)-1,5-diazecane

Guidance literature:: With caesium carbonate; In acetonitrile; at 80 ℃; for 24h; Inert atmosphere;
DOI:10.1021/ol5010033

Reference yield:

: 1609184-06-6
(S)-N-(5-(N-allyloxycarbonyl-2-nitrobenzenesulfonamido)-2-methylenepentyl)-N-glycidyl-2-nitrobenzenesulfonamide

: 1609184-22-6
(S)-7-methylene-3-(2-nitrophenoxy)-1-(2-nitrobenzenesulfonyl)-1,5-diazecane

Guidance literature:: Multi-step reaction with 3 steps

1: HSiPh₃; tetrakis(triphenylphosphine) palladium⁽⁰⁾; acetic acid / 2 h / 20 °C / Inert atmosphere

2: caesium carbonate / acetonitrile / 24 h / 80 °C / Inert atmosphere

3: caesium carbonate / acetonitrile / 4 h / 80 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; acetic acid; HSiPh₃; In acetonitrile; 3: |Smiles Aromatic Rearrangement;
DOI:10.1021/ol5010033