C₅₄H₇₄N₃OS₄⁽¹⁺⁾*I^(1-)

Base Information

• Chemical Name: C₅₄H₇₄N₃OS₄⁽¹⁺⁾*I^(1-)
• CAS No.: 1563057-66-8
• Molecular Formula: C₅₄H₇₄N₃OS₄*I
• Molecular Weight: 1036.37
• Mol file: 1563057-66-8.mol

Synonyms:C₅₄H₇₄N₃OS₄⁽¹⁺⁾*I^(1-)

Chemical Property of C₅₄H₇₄N₃OS₄⁽¹⁺⁾*I^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₄H₇₄N₃OS₄⁽¹⁺⁾*I^(1-)

There total 6 articles about C₅₄H₇₄N₃OS₄⁽¹⁺⁾*I^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

2-[2-[2-chloro-3-[(1,3-dihydro-3,3-dimethyl-1-propyl-2H-indolyl-2-ylidenyl)ethylidenyl]-1-cyclohexen-1-yl]ethenyl]-3,3-dimethyl-1-propylindolium iodide (207399-07-3) + N,N-bis(3,6-dithiaoctyl)-p-aminophenol (1563057-62-4) → C54H74N3OS4(1+)*I(1-) (1563057-66-8)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 20 ℃; for 16h; Inert atmosphere;

Reference yield:

4-methoxy-aniline (104-94-9) → C54H74N3OS4(1+)*I(1-) (1563057-66-8)

Guidance literature:

Multi-step reaction with 6 steps

1.1: sodium iodide; potassium carbonate / acetonitrile / 17 h / Reflux

2.1: lithium aluminium tetrahydride / tetrahydrofuran / 24 h / 0 °C / Reflux

3.1: 1,1,1-tribromoethane; triphenylphosphine / tetrahydrofuran / 6 h / 20 °C / Inert atmosphere

4.1: sodium / ethanol / 0.5 h / Reflux; Inert atmosphere

4.2: 16 h / Inert atmosphere; Reflux

5.1: boron tribromide / dichloromethane / 16 h / 0 - 20 °C

6.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 16 h / 20 °C / Inert atmosphere

With lithium aluminium tetrahydride; 1,1,1-tribromoethane; sodium; boron tribromide; sodium hydride; potassium carbonate; triphenylphosphine; sodium iodide; In tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide; acetonitrile; mineral oil;

Reference yield:

diethyl 2,2’-((4-methoxyphenyl)azanediyl)diacetate (98269-30-8) → C54H74N3OS4(1+)*I(1-) (1563057-66-8)

Guidance literature:

Multi-step reaction with 5 steps

1.1: lithium aluminium tetrahydride / tetrahydrofuran / 24 h / 0 °C / Reflux

2.1: 1,1,1-tribromoethane; triphenylphosphine / tetrahydrofuran / 6 h / 20 °C / Inert atmosphere

3.1: sodium / ethanol / 0.5 h / Reflux; Inert atmosphere

3.2: 16 h / Inert atmosphere; Reflux

4.1: boron tribromide / dichloromethane / 16 h / 0 - 20 °C

5.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 16 h / 20 °C / Inert atmosphere

With lithium aluminium tetrahydride; 1,1,1-tribromoethane; sodium; boron tribromide; sodium hydride; triphenylphosphine; In tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide; mineral oil;

upstream raw materials:

2-[2-[2-chloro-3-[(1,3-dihydro-3,3-dimethyl-1-propyl-2H-indolyl-2-ylidenyl)ethylidenyl]-1-cyclohexen-1-yl]ethenyl]-3,3-dimethyl-1-propylindolium iodide

N,N-bis(3,6-dithiaoctyl)-p-aminophenol

4-methoxy-aniline

diethyl 2,2’-((4-methoxyphenyl)azanediyl)diacetate