tert-Butyl-diphenyl-[(Z)-(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-non-3-enyloxy]-silane

Base Information

Chemical Name:tert-Butyl-diphenyl-[(Z)-(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-non-3-enyloxy]-silane
CAS No.:89084-42-4
Molecular Formula:C₃₁H₄₆O₃Si
Molecular Weight:494.79
Hs Code.:

Synonyms:tert-Butyl-diphenyl-[(Z)-(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-non-3-enyloxy]-silane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of tert-Butyl-diphenyl-[(Z)-(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-non-3-enyloxy]-silane

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of tert-Butyl-diphenyl-[(Z)-(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-non-3-enyloxy]-silane

There total 10 articles about tert-Butyl-diphenyl-[(Z)-(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-non-3-enyloxy]-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 4762-26-9
hexyltriphenylphosphonium bromide

: 89084-41-3
(R)-3-(tert-Butyl-diphenyl-silanyloxy)-3-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-propionaldehyde

: 89084-42-4
tert-Butyl-diphenyl-[(Z)-(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-non-3-enyloxy]-silane

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; N,N-dimethyl-formamide; at -100 ℃;
DOI:10.1016/S0040-4039(00)88418-X

Reference yield:

: 82010-51-3
(4S)-cis-2,2,5-trimethyl-1,3-dioxolane-4-carboxaldehyde

: 89084-42-4
tert-Butyl-diphenyl-[(Z)-(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-non-3-enyloxy]-silane

Guidance literature:: Multi-step reaction with 4 steps

2: 80 percent / DMAP, Et₃N / 72 h / Ambient temperature

3: 2.) Ph₃P / 1.) ozonolysis

4: 45 percent / t-BuOK / tetrahydrofuran; dimethylformamide / -100 °C

With dmap; potassium tert-butylate; triethylamine; triphenylphosphine; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)88418-X

Reference yield:

: 110-53-2
1-Bromopentane

: 89084-42-4
tert-Butyl-diphenyl-[(Z)-(R)-1-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-non-3-enyloxy]-silane

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide

2: H₂ / Lindlar catalyst

With n-butyllithium; hydrogen; Lindlar's catalyst; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide;
DOI:10.1016/S0040-4039(00)88418-X