110-53-2Relevant articles and documents
Brewer,Greensfelder
, p. 2257 (1951)
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Kharasch et al.
, p. 1659 (1952)
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Silica Supported Acids (HClO4-SiO2, KHSO4-SiO2) as Eco-friendly Reusable Catalysts for Bromodecarboxylation of α,β-Unsaturated Carboxylic Acids using KBr under Solvothermal and Solvent-Free Conditions
Arisha, Samba Shiva Rao,Gugulothu, Yaku,Kamatala, Chinna Rajanna,Nagannagari, Maasi Reddy,Pulusu, Vijay Shekar,Utkoor, Umesh Kumar,Yelike, Hemanth Sriram
, p. 535 - 542 (2022/02/22)
A mild procedure has been developed for the bromodecarboxylation of α,β-carboxylic acids using nano silica supported SiO2-HClO4, SiO2-KHSO4 as catalysts and KBr as a bromine source in conventional solvothermal, ultrasonic assisted and solvent-free microwave assisted conditions. The α,β-unsaturated cinnamic acids were converted to corresponding β-bromo styrenes with high regioselectivity, while aliphatic α,β-unsaturated carboxylic acids afforded related β-bromo alkenes.
Facile continuous process for gas phase halogen exchange over supported alkyl phosphonium salts
Sharma, Priti,Sasson, Yoel
, p. 2824 - 2828 (2018/02/06)
Chloride-bromide halogen exchange was realized when a mixture of an alkyl chloride and an alkyl bromide were reacted over a supported molten alkyl phosphonium catalyst. Conversion was found to be near equilibrium in a tubular flow reactor at 150 °C and 1500 GHSV. The catalyst was prepared by impregnation of alumina or silica support and found to be highly stable for relatively long periods of time. A pathway for the catalytic cycle is proposed.
A mild method for the replacement of a hydroxyl group by halogen. 1. Scope and chemoselectivity
Munyemana, Fran?ois,George, Isabelle,Devos, Alain,Colens, Alain,Badarau, Eduard,Frisque-Hesbain, Anne-Marie,Loudet, Aurore,Differding, Edmond,Damien, Jean-Marie,Rémion, Jeanine,Van Uytbergen, Jacqueline,Ghosez, Léon
, p. 420 - 430 (2015/12/31)
α-Chloro-, bromo- and iodoenamines, which are readily prepared from the corresponding isobutyramides have been found to be excellent reagents for the transformation of a wide variety of alcohols or carboxylic acids into the corresponding halides. Yields are high and conditions are very mild thus allowing for the presence of sensitive functional groups. The reagents can be easily tuned allowing therefore the selective monohalogenation of polyhydroxylated molecules. The scope and chemoselectivity of the reactions have been studied and reaction mechanisms have been proposed.