(bis(2-diphenylphosphino)phenyl ether)(1,4,8,9-tetraaza-benzo[b]triphenylene)copper(I) tetrafluoroborate

Base Information

• Chemical Name: (bis(2-diphenylphosphino)phenyl ether)(1,4,8,9-tetraaza-benzo[b]triphenylene)copper(I) tetrafluoroborate
• CAS No.: 1251467-84-1
• Molecular Formula: BF₄*C₅₄H₃₈CuN₄OP₂
• Molecular Weight: 971.22
• Mol file: 1251467-84-1.mol

Synonyms:(bis(2-diphenylphosphino)phenyl ether)(1,4,8,9-tetraaza-benzo[b]triphenylene)copper(I) tetrafluoroborate

Chemical Property of (bis(2-diphenylphosphino)phenyl ether)(1,4,8,9-tetraaza-benzo[b]triphenylene)copper(I) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (bis(2-diphenylphosphino)phenyl ether)(1,4,8,9-tetraaza-benzo[b]triphenylene)copper(I) tetrafluoroborate

There total 3 articles about (bis(2-diphenylphosphino)phenyl ether)(1,4,8,9-tetraaza-benzo[b]triphenylene)copper(I) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dipyridil[3,2-a:2',3'-c]phenazine (19535-47-8) + tetrakis(acetonitrile)copper(I)tetrafluoroborate + bis[2-(diphenylphosphino)phenyl] ether (166330-10-5) → (bis(2-diphenylphosphino)phenyl ether)(1,4,8,9-tetraaza-benzo[b]triphenylene)copper(I) tetrafluoroborate (1251467-84-1)

Guidance literature:

tetrakis(acetonitrile)copper(I)tetrafluoroborate; bis[2-(diphenylphosphino)phenyl] ether; In dichloromethane; for 0.5h;

dipyridil[3,2-a:2',3'-c]phenazine; for 0.5h;

DOI:10.1016/j.saa.2020.118537

Reference yield:

1,10-Phenanthroline (66-71-7) → (bis(2-diphenylphosphino)phenyl ether)(1,4,8,9-tetraaza-benzo[b]triphenylene)copper(I) tetrafluoroborate (1251467-84-1)

Guidance literature:

Multi-step reaction with 3 steps

1.1: nitric acid; sulfuric acid; potassium bromide

2.1: ethanol / 10 h / Heating

3.1: dichloromethane / 0.5 h

3.2: 0.5 h

With sulfuric acid; nitric acid; potassium bromide; In ethanol; dichloromethane;

DOI:10.1016/j.saa.2020.118537

Reference yield:

1,10-phenanthroline-5,6-dione (27318-90-7) → (bis(2-diphenylphosphino)phenyl ether)(1,4,8,9-tetraaza-benzo[b]triphenylene)copper(I) tetrafluoroborate (1251467-84-1)

Guidance literature:

Multi-step reaction with 2 steps

1.1: ethanol / 10 h / Heating

2.1: dichloromethane / 0.5 h

2.2: 0.5 h

In ethanol; dichloromethane;

DOI:10.1016/j.saa.2020.118537

upstream raw materials:

1,10-phenanthroline-5,6-dione

1,10-Phenanthroline

dipyridil[3,2-a:2',3'-c]phenazine

bis[2-(diphenylphosphino)phenyl] ether