C-UNDECYLCALIX(4)RESORCINARENE CH3OH

Base Information

• Chemical Name: C-UNDECYLCALIX(4)RESORCINARENE CH3OH
• CAS No.: 116780-43-9
• Molecular Formula: C72H112 O8
• Molecular Weight: 1105.68
• Mol file: 116780-43-9.mol

Synonyms:C-Undecylcalix[4]resorcinarene;Tetra-n-undecylcalix[4]resorcinarene

Chemical Property of C-UNDECYLCALIX(4)RESORCINARENE CH3OH

Chemical Property:

• Melting Point: 285 °C
• Boiling Point: 1082.7±60.0 °C(Predicted)
• PKA: 9.15±0.70(Predicted)
• PSA: 57.15000
• Density: 1.039±0.06 g/cm3(Predicted)
• LogP: 23.07090

Purity/Quality:

97% ^*data from raw suppliers

C-UNDECYLCALIX(4)RESORCINARENE CH3OH 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of C-UNDECYLCALIX(4)RESORCINARENE CH3OH

There total 1 articles about C-UNDECYLCALIX(4)RESORCINARENE CH3OH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

Dodecanal (112-54-9) + recorcinol (108-46-3) → C-undecyl resorcin[4]arene (116780-43-9,112247-07-1)

Guidance literature:

With Yb(OTf)₃*9H₂O; In ethanol; for 48h; Heating;

Reference yield: 99.0%

C-undecyl resorcin[4]arene (116780-43-9,112247-07-1) + 4-chloro-benzoyl chloride (122-01-0) → C128H136Cl8O16 (1328884-39-4)

Guidance literature:

With pyridine; at 20 ℃; for 2h; regioselective reaction;

DOI:10.1021/ol201919p

Reference yield: 93.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + C-undecyl resorcin[4]arene (116780-43-9,112247-07-1) + benzylamine (100-46-9) → C108H148N4O8

Guidance literature:

With water; In ethanol; toluene; Heating;

DOI:10.1021/ja00116a039

upstream raw materials:

Dodecanal

recorcinol

Refernces

• 1、 Merget, Severin,Catti, Lorenzo,Piccini, Giovannimaria,Tiefenbacher, Konrad. "Requirements for Terpene Cyclizations inside the Supramolecular Resorcinarene Capsule: Bound Water and Its Protonation Determine the Catalytic Activity". supporting information. p. 4400 - 4410. Retrieved 2020/03/04.
• 2、 Catti, Lorenzo,Tiefenbacher, Konrad. "Br?nsted Acid-Catalyzed Carbonyl-Olefin Metathesis inside a Self-Assembled Supramolecular Host". supporting information. p. 14589 - 14592. Retrieved 2018/01/27.