Technology Process of [Rh(C8H12)(C6H4(P(C6H5)2)C(OH)NC6H5)](1+)*ClO4(1-)=[Rh(C8H12)(C6H4(P(C6H5)2)C(OH)NC6H5)]ClO4
There total 1 articles about [Rh(C8H12)(C6H4(P(C6H5)2)C(OH)NC6H5)](1+)*ClO4(1-)=[Rh(C8H12)(C6H4(P(C6H5)2)C(OH)NC6H5)]ClO4 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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With
AgClO4;
In
tetrahydrofuran;
byproducts: AgCl; addn. of dry oxygen-free THF to the Rh compd. and AgClO4 in a Schlenk vessel, stirring for 20 min, filtn. under N2, addn. of the ligand in dry oxygen-free THF, stirring for 20 min and dissolving of the solid in N2-satd. CH2Cl2; filtn. under N2, dropwise addn. of N2-satd. hexane, vac. filtn. under N2 and drying (vac.);