((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3⁽¹⁺⁾*BF₄^(1-)=((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3BF₄

Base Information

• Chemical Name: ((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3⁽¹⁺⁾*BF₄^(1-)=((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3BF₄
• CAS No.: 96454-53-4
• Molecular Formula: BF₄*C₃₇H₃₁O₃P₂W
• Molecular Weight: 859.22

Synonyms:((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3⁽¹⁺⁾*BF₄^(1-)=((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3BF₄

Chemical Property of ((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3⁽¹⁺⁾*BF₄^(1-)=((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3BF₄

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Technology Process of ((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3⁽¹⁺⁾*BF₄^(1-)=((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3BF₄

There total 1 articles about ((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3⁽¹⁺⁾*BF₄^(1-)=((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)3BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[((C6H5)2PCH2)2W(CCH2C6H5)(CO)2](1+)*BF4(1-)=((C6H5)2PCH2CH2P(C6H5)2)W(CCH2C6H5)(CO)2BF4 (96454-61-4) + [13C]Carbon monoxide (1641-69-6) → ((C6H5)2PCH2CH2P(C6H5)2)W(CCH2C6H5)((13)CO)3(1+)*BF4(1-)=((C6H5)2PCH2CH2P(C6H5)2)W(CCH2C6H5)((13)CO)3BF4 (96454-53-4)

Guidance literature:

In dichloromethane; a soln. of the complex was frozen in a liquid N2 bath, the flask was evacuated and filled with 1 atm of (13)CO, the mixt. was warmed to room temp. and stirred under (13)CO for 6 h; (13)CO enrichment was detd. by IR spectrum;

DOI:10.1021/ja00301a017

Reference yield:

((C6H5)2PCH2CH2P(C6H5)2)W(CCH2C6H5)((13)CO)3(1+)*BF4(1-)=((C6H5)2PCH2CH2P(C6H5)2)W(CCH2C6H5)((13)CO)3BF4 (96454-53-4) → ((C6H5)2PCH2CH2P(C6H5)2)W(C6H5CCH)((13)CO)3 (96481-29-7)

Guidance literature:

With Al₂O₃; In dichloromethane; a soln. of the complex was cooled to 0°C, Al2O3 was added, the mixt. was stirred under N2 (IR monitoring), the soln. was sepd. from Al2O3 by extg., solvent was removed in vacuo, the green solid was extd. withtoluene and triturated with pentane; identified by IR and NMR spectra;

DOI:10.1021/ja00301a017

Reference yield:

((C6H5)2PCH2CH2P(C6H5)2)W(CCH2C6H5)((13)CO)3(1+)*BF4(1-)=((C6H5)2PCH2CH2P(C6H5)2)W(CCH2C6H5)((13)CO)3BF4 (96454-53-4) → [((C6H5)2PCH2)2W((13)CO)2(CCH2C6H5)](1+)*BF4(1-)=((C6H5)2PCH2CH2P(C6H5)2)W(CCH2C6H5)((13)CO)2BF4 (96454-63-6)

Guidance literature:

In dichloromethane; byproducts: (13)CO; refluxing under N2 for 24 h; identified by IR spectrum;

DOI:10.1021/ja00301a017

upstream raw materials:

[((C₆H₅)2PCH₂)2W(CCH₂C₆H₅)(CO)2]⁽¹⁺⁾*BF₄^(1-)=((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(CO)2BF₄

[13C]Carbon monoxide

Downstream raw materials:

[((C₆H₅)2PCH₂)2W(⁽¹³⁾CO)2(CCH₂C₆H₅)]⁽¹⁺⁾*BF₄^(1-)=((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH₂C₆H₅)(⁽¹³⁾CO)2BF₄

((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(C₆H₅CCH)(⁽¹³⁾CO)3

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