Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)

Base Information

Chemical Name:Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)
CAS No.:116128-29-1
Molecular Formula:C₅₂H₄₆O₄P₂Ru
Molecular Weight:897.952
Hs Code.:
Mol file:116128-29-1.mol

Synonyms:Ruthenium,bis(acetato-O,O')[[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine]-P,P']-,[OC-6-22-(R)]-; Phosphine,[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)-, ruthenium complex, (R)-

Suppliers and Price of Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Ru(OAc)2[(s)-tolbinap]
100mg
$ 75.00

TCI Chemical
Ru(OAc)2[(R)-tolbinap]
1g
$ 160.00

TCI Chemical
Ru(OAc)2[(R)-tolbinap]
200mg
$ 48.00

Strem Chemicals
Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-tolbinap]
250mg
$ 53.00

Strem Chemicals
Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-tolbinap]
5g
$ 379.00

Strem Chemicals
Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-tolbinap]
1g
$ 158.00

Sigma-Aldrich
(R)-Ru(OAc)2(T-BINAP)
500mg
$ 81.10

Sigma-Aldrich
(R)-Ru(OAc)2(T-BINAP)
100mg
$ 26.30

Chem-Impex
Ru(OAc)2[(R)-tolbinap]
200MG
$ 51.25

Chemenu
Diacetato[(R)-(+)-2,2''-bis(di-p-tolylphosphino)-1,1''-binaphthyl]ruthenium(II) 95%
1g
$ 280.00

Total 18 raw suppliers

Chemical Property of Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)

Chemical Property:

Melting Point:>100°C
PSA：107.44000
LogP:7.92240
Storage Temp.:2-8°C
Sensitive.:air sensitive

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ru(OAc)2[(s)-tolbinap] ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses Ru(OAc)2[(S)-tolbinap] is used as a catalyst.

Technology Process of Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)

There total 4 articles about Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 153305-67-0,100165-88-6,99646-28-3
(+)-(R)-2,2'bis(di-para-tolylphosphanyl)-1,1'binaphthyl

: dichloro(1,5-cyclooctadiene)ruthenium(II)

: 112065-78-8,114818-53-0,106681-15-6,116128-29-1
diacetato[(S)-(-)-2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl]ruthenium(II)

Guidance literature:: With sodium acetate; triethylamine; In toluene; tert-butyl alcohol; react. of (RuCl2(cod))2 with (S)-BINAP-derivative and N(C2H5)3 in toluene, then addn. of NaO2CCH3;;

Reference yield:

: 153305-67-0,100165-88-6,99646-28-3
(R)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl

: dichloro(1,5-cyclooctadiene)ruthenium(II)

: 112065-78-8,114818-53-0,106681-15-6,116128-29-1
diacetato[(R)-(+)-2,2-bis(di-p-tolylphosphono)-1,1′?binaphthyl]ruthenium(II)

Guidance literature:: With sodium acetate; triethylamine; In toluene; tert-butyl alcohol; react. of (RuCl2(cod))2 with (R)-BINAP-derivative and N(C2H5)3 in toluene, then addn. of sodium acetate;;