(5S)-2,3-dimethyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-one

Base Information

Chemical Name:(5S)-2,3-dimethyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-one
CAS No.:85710-66-3
Molecular Formula:C₁₁H₁₈O
Molecular Weight:166.263
Hs Code.:
European Community (EC) Number:890-099-4
Nikkaji Number:J331.777C

Synonyms:(5S)-2,3-dimethyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-one;85710-66-3;(5S)-2,3-dimethyl-5-prop-1-en-2-ylcyclohex-2-en-1-one;EN300-1611720;(S)-2,3-Dimethyl-5alpha-isopropenyl-2-cyclohexene-1-one

Suppliers and Price of (5S)-2,3-dimethyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of (5S)-2,3-dimethyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-one

Chemical Property:

XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:164.120115130
Heavy Atom Count:12
Complexity:258

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=C(C(=O)CC(C1)C(=C)C)C
Isomeric SMILES:CC1=C(C(=O)C[C@H](C1)C(=C)C)C

Technology Process of (5S)-2,3-dimethyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-one

There total 8 articles about (5S)-2,3-dimethyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 917-64-6
methyl magnesium iodide

: 6485-40-1,2244-16-8
(R)-Carvone

: 85710-65-2,85710-66-3
(5S)-2,3-Dimethyl-5-isopropenylcyclohex-2-en-1-one

Guidance literature:: methyl magnesium iodide; (R)-Carvone; In diethyl ether; at 0 - 20 ℃; for 1h;

With silica gel; pyridinium chlorochromate; In dichloromethane; at 20 ℃; for 4h;
DOI:10.1016/j.tetasy.2005.07.030

Reference yield: 92.0%

: 143612-00-4
(-)-(1S,4S,6S)-4-isopropenyl-1,6-dimethyl-7-oxabicyclo[4.1.0]heptan-2-one

: 85710-65-2,85710-66-3
(5S)-2,3-Dimethyl-5-isopropenylcyclohex-2-en-1-one

Guidance literature:: With sodium hydroxide; thiourea dioxide; tetrabutylammomium bromide; In tetrahydrofuran; at 50 ℃; for 0.5h;
DOI:10.1016/S0040-4039(96)02451-3

Reference yield: 89.0%

: 852930-25-7
(R)-2-methylcarveol

: 85710-65-2,85710-66-3
(5S)-2,3-Dimethyl-5-isopropenylcyclohex-2-en-1-one

Guidance literature:: With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; copper(II) choride dihydrate; In acetonitrile; at 20 ℃; for 48h; chemoselective reaction; Molecular sieve;
DOI:10.1016/j.tet.2009.11.104