C₅₃H₇₀N₂NiO

Base Information

Chemical Name:C₅₃H₇₀N₂NiO
CAS No.:1364809-07-3
Molecular Formula:C₅₃H₇₀N₂NiO
Molecular Weight:809.842
Hs Code.:

C<sub>53</sub>H<sub>70</sub>N<sub>2</sub>NiO

Synonyms:C₅₃H₇₀N₂NiO

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Chemical Property of C₅₃H₇₀N₂NiO

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Technology Process of C₅₃H₇₀N₂NiO

There total 7 articles about C₅₃H₇₀N₂NiO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 110-86-1
pyridine

: dimethyl(tetramethylethylenediamine)nickel(II)

: 1364808-99-0
(CH(CH₃)2)2C₆H₃NCHC(CH₃)3OHC₆H₂C₆(CH₃)4C₆H₃(C(CH₃)3)2

: 1364809-07-3
(CH(CH₃)2)2C₆H₃NCHC(CH₃)3OC₆H₂C₆(CH₃)4C₆H₃(C(CH₃)3)2Ni(CH₃)C₅H₅N

Guidance literature:: In diethyl ether; byproducts: CH4, N,N,N',N'-tetramethylethylenediamine; under an inert atm.; a soln. of a ligand (0.14 mmol) in Et2O and a soln.of Ni-contg. compd. (0.15 mmol) in Et2O were cooled to ca. -35°C ; the soln. of the ligand was added to the soln. of Ni-contg. compd.; pyridine (1.52 mmol) was added; after stirring for 6 h at room temp. volatiles were removed under vac.; the suspn. was washed over Celite with hexanes; volatiles were removed from the filtrate under vac.; pptn. from pentane; elem. anal.;
DOI:10.1021/om2011694

Reference yield:

: 110-86-1
pyridine

: dimethyl(tetramethylethylenediamine)nickel(II)

: 1364808-99-0
(CH(CH₃)2)2C₆H₃NCHC(CH₃)3OHC₆H₂C₆(CH₃)4C₆H₃(C(CH₃)3)2

: 1364809-07-3
C₅₃H₇₀N₂NiO

Guidance literature:: In diethyl ether; at -35 - 20 ℃;

Reference yield:

: 1364808-87-6
C₂₂H₂₉BrO₂

: 1364809-07-3
C₅₃H₇₀N₂NiO

Guidance literature:: Multi-step reaction with 5 steps

1: tert.-butyl lithium

2: N,N,N,N,-tetramethylethylenediamine; n-butyllithium / tetrahydrofuran

3: hydrogenchloride / water; methanol

4: toluene-4-sulfonic acid / methanol; dichloromethane

5: diethyl ether / -35 - 20 °C

With hydrogenchloride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; tert.-butyl lithium; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; 1: |Negishi Coupling;