phenyl 3,4-di-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->6)-3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:phenyl 3,4-di-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->6)-3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside
CAS No.:1322656-55-2
Molecular Formula:C₄₄H₄₁ClN₂O₁₇S
Molecular Weight:937.332
Hs Code.:

phenyl 3,4-di-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->6)-3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Synonyms:phenyl 3,4-di-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->6)-3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

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Chemical Property of phenyl 3,4-di-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->6)-3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

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Technology Process of phenyl 3,4-di-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->6)-3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

There total 5 articles about phenyl 3,4-di-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->6)-3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₀H₁₉BrClNO₉

: 225242-46-6
phenyl 3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

: 1322656-55-2
phenyl 3,4-di-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->6)-3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Guidance literature:: C₂₀H₁₉BrClNO₉; phenyl 3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside; With 2,4,6-trimethyl-pyridine; In dichloromethane; at -74 ℃; for 0.5h; Molecular sieve;

With silver trifluoromethanesulfonate; In dichloromethane; toluene; at -74 - 20 ℃; Molecular sieve;
DOI:10.1016/j.carres.2011.03.029

Reference yield:

: 1322656-53-0
C₄₃H₃₇NO₈S

: 1322656-55-2
phenyl 3,4-di-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->6)-3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: acetic acid / water / 3 h / 50 °C

2.1: 2,4,6-trimethyl-pyridine / dichloromethane / 0.5 h / -74 °C / Molecular sieve

2.2: -74 - 20 °C / Molecular sieve

With 2,4,6-trimethyl-pyridine; acetic acid; In dichloromethane; water;
DOI:10.1016/j.carres.2011.03.029

Reference yield:

: 136882-36-5,79528-50-0
2-((2S,3R,4R,5S,6R)-4,5-Dihydroxy-6-hydroxymethyl-2-phenylsulfanyl-tetrahydro-pyran-3-yl)-isoindole-1,3-dione

: 1322656-55-2
phenyl 3,4-di-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->6)-3,4-di-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: dmap / pyridine / 24 h / 20 °C

2.1: pyridine / 24 h / 20 °C

3.1: acetic acid / water / 3 h / 50 °C

4.1: 2,4,6-trimethyl-pyridine / dichloromethane / 0.5 h / -74 °C / Molecular sieve

4.2: -74 - 20 °C / Molecular sieve

With 2,4,6-trimethyl-pyridine; dmap; acetic acid; In pyridine; dichloromethane; water;
DOI:10.1016/j.carres.2011.03.029