TRIS(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM (II) TRIFLUOROMETHANESULFONATE

Base Information

• Chemical Name: TRIS(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM (II) TRIFLUOROMETHANESULFONATE
• CAS No.: 113860-02-9
• Molecular Formula: C17H24F3N3O3RuS5*-
• Molecular Weight: 508.527
• Mol file: 113860-02-9.mol

Synonyms:TRIS(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM (II) TRIFLUOROMETHANESULFONATE;TRIS(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM (II) TRIFLUOROMETHANESULFONATE, MIN. 98%;Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II)trifluoromethanesulfonate,min.98%;Tris(acetonitrile)pentaMethylcyclopentadienylrutheniuM(II) trifluoroMethanesulfonate,98%

Chemical Property of TRIS(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM (II) TRIFLUOROMETHANESULFONATE

Chemical Property:

• PSA: 136.95000
• LogP: 5.69384
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: air sensitive, store cold

Purity/Quality:

99% ^*data from raw suppliers

Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) trifluoromethanesulfonate, min. 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/37/38:
• Hazard Codes: R36/37/38:
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIS(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM (II) TRIFLUOROMETHANESULFONATE

There total 5 articles about TRIS(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM (II) TRIFLUOROMETHANESULFONATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

chloro(pentamethylcyclopentadienyl)ruthenium(II) tetramer (126821-58-7) + silver trifluoromethanesulfonate (2923-28-6) + acetonitrile (75-05-8,26809-02-9) → [Cp*Ru(CH3CN)3]OTf (113860-02-9)

Guidance literature:

In acetonitrile; byproducts: AgCl; refluxing for 1 h, cooling to room temp.; filtn., washing (diethyl ether), drying in vac., elem. anal.;

DOI:10.1021/ja00187a024

Reference yield: 94.0%

chloro(pentamethylcyclopentadienyl)ruthenium(II) tetramer (126821-58-7) → [Cp*Ru(CH3CN)3]OTf (113860-02-9)

Guidance literature:

With Ag(OSO₂CF₃); In acetonitrile; Refluxing, 2 h, AgOTf added.; Filtd., evapd., ether added.;

DOI:10.1021/ja00217a054

Reference yield: 63.0%

trans-(endo-η5-pentamethylcyclopentdienyl)(η6-9,10-dihydroanthracene-9,10-α,β-succinic anhydride)ruthenium triflate → [Cp*Ru(CH3CN)3]OTf (113860-02-9) + dibenzobarallene (103515-22-6)

Guidance literature:

In acetonitrile; Irradiation (UV/VIS); irradiation of a soln. of Ru-complex in dry MeCN with stirring and without cooling for 3 days under N2; removal of solvent under reduced pressure, extn. with Et2O (three times), drying under reduced pressure gives Ru-complex, concn. of Et2O soln., column chromy., elution (CH2Cl2), removal of solvent gives succinic acid anhydride, elem. anal.;

DOI:10.1021/om00013a046

upstream raw materials:

acetonitrile

chloro(pentamethylcyclopentadienyl)ruthenium(II) tetramer

silver trifluoromethanesulfonate

Downstream raw materials:

((C₅(CH₃)5)Ru(CO)((C₆H₅)2PCH₂CH₂NH₂))⁽¹⁺⁾*CF₃SO₃^(1-)=((C₅(CH₃)5)Ru(CO)((C₆H₅)2PCH₂CH₂NH₂))(CF₃SO₃)

[Cp*Ru{η⁵-(benzyl)₂(aminofulvene-formaldiminate)}H][triflate]

[Ru(η5-C5Me5)(MeCN)(κ3(P,C,C)-Ph2PCH2CH=CH2)][OTf]