allyl 2-[2-{3,4-bis(triisopropylsilyloxy)benzyloxy}-3-(methoxymethoxy)phenyl]acetate

Base Information

Chemical Name:allyl 2-[2-{3,4-bis(triisopropylsilyloxy)benzyloxy}-3-(methoxymethoxy)phenyl]acetate
CAS No.:1609691-93-1
Molecular Formula:C₃₈H₆₂O₇Si₂
Molecular Weight:687.077
Hs Code.:

Synonyms:allyl 2-[2-{3,4-bis(triisopropylsilyloxy)benzyloxy}-3-(methoxymethoxy)phenyl]acetate

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Chemical Property of allyl 2-[2-{3,4-bis(triisopropylsilyloxy)benzyloxy}-3-(methoxymethoxy)phenyl]acetate

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Technology Process of allyl 2-[2-{3,4-bis(triisopropylsilyloxy)benzyloxy}-3-(methoxymethoxy)phenyl]acetate

There total 7 articles about allyl 2-[2-{3,4-bis(triisopropylsilyloxy)benzyloxy}-3-(methoxymethoxy)phenyl]acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1609691-92-0
2-[2-{3,4-bis(triisopropylsilyloxy)benzyloxy}-3-(methoxymethoxy)phenyl]acetic acid

: 106-95-6
allyl bromide

: 1609691-93-1
allyl 2-[2-{3,4-bis(triisopropylsilyloxy)benzyloxy}-3-(methoxymethoxy)phenyl]acetate

Guidance literature:: With caesium carbonate; In N,N-dimethyl-formamide; at 0 - 2 ℃; for 2h; Inert atmosphere;
DOI:10.1055/s-0033-1340291

Reference yield:

: 1126-20-1
2-allyloxyphenol

: 1609691-93-1
allyl 2-[2-{3,4-bis(triisopropylsilyloxy)benzyloxy}-3-(methoxymethoxy)phenyl]acetate

Guidance literature:: Multi-step reaction with 7 steps

1: N-ethyl-N,N-diisopropylamine / acetonitrile / 6 h / 50 °C / Inert atmosphere

2: 18 h / 180 °C / Microwave irradiation; Inert atmosphere

3: diethylazodicarboxylate; triphenylphosphine / toluene; tetrahydrofuran; diethyl ether / 6 h / 0 - 20 °C / Inert atmosphere

4: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; diethyl ether; tert-butyl alcohol / 3 h / 0 - 20 °C

5: sodium periodate / water; diethyl ether / 6 h / 0 - 20 °C

6: 2-methyl-but-2-ene; sodium dihydrogenphosphate; sodium chlorite / water; diethyl ether; tert-butyl alcohol / 1.5 h

7: caesium carbonate / N,N-dimethyl-formamide / 2 h / 0 - 2 °C / Inert atmosphere

With sodium chlorite; sodium periodate; sodium dihydrogenphosphate; osmium(VIII) oxide; 2-methyl-but-2-ene; caesium carbonate; 4-methylmorpholine N-oxide; N-ethyl-N,N-diisopropylamine; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; diethyl ether; water; N,N-dimethyl-formamide; toluene; acetonitrile; tert-butyl alcohol; 2: |Claisen Rearrangement / 3: |Mitsunobu Displacement;
DOI:10.1055/s-0033-1340291

Reference yield:

: C₃₅H₅₈O₆Si₂

: 1609691-93-1
allyl 2-[2-{3,4-bis(triisopropylsilyloxy)benzyloxy}-3-(methoxymethoxy)phenyl]acetate

Guidance literature:: Multi-step reaction with 2 steps

1: 2-methyl-but-2-ene; sodium dihydrogenphosphate; sodium chlorite / water; diethyl ether; tert-butyl alcohol / 1.5 h

2: caesium carbonate / N,N-dimethyl-formamide / 2 h / 0 - 2 °C / Inert atmosphere

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; caesium carbonate; In diethyl ether; water; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1055/s-0033-1340291