(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)⁽¹⁺⁾*BF₄^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)]BF₄

Base Information

• Chemical Name: (CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)⁽¹⁺⁾*BF₄^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)]BF₄
• CAS No.: 180320-96-1
• Molecular Formula: BF₄*C₄₅H₄₁O₂P₃Re
• Molecular Weight: 979.752

Synonyms:(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)⁽¹⁺⁾*BF₄^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)]BF₄

Chemical Property of (CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)⁽¹⁺⁾*BF₄^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)⁽¹⁺⁾*BF₄^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)]BF₄

There total 2 articles about (CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)⁽¹⁺⁾*BF₄^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

(CH3C(CH2P(C6H5)2)3)Re(CO)2(H) (166989-33-9) + tetrafluoroboric acid dimethyl ether complex (67969-83-9) + trimethylsilylacetylene (1066-54-2) → (CH3C(CH2P(C6H5)2)3)Re(CO)2(CCH2)(1+)*BF4(1-)=[(CH3C(CH2P(C6H5)2)3)Re(CO)2(CCH2)]BF4 (180320-96-1)

Guidance literature:

With HBF₄ * OMe₂; In dichloromethane; N2-atmosphere; stirring (-10°C, 30 min); evapn. (vac.), washing (EtOH, n-pentane), crystn. (CH2Cl2 / n-hexane); elem. anal.;

DOI:10.1021/om9602264

Reference yield: 90.0%

[(MeC(CH2PPh2)3)Re(CO)2(η(2)-H2)]BF4 (166989-35-1) + acetylene (74-86-2,25067-58-7) → (CH3C(CH2P(C6H5)2)3)Re(CO)2(CCH2)(1+)*BF4(1-)=[(CH3C(CH2P(C6H5)2)3)Re(CO)2(CCH2)]BF4 (180320-96-1)

Guidance literature:

In dichloromethane; C2H2-bubbling (0°C, 1 min), stirring (N2-atmosphere, room temp., 30 min); evapn. (vac.), crystn. (CH2Cl2 / n-hexane); elem. anal.;

DOI:10.1021/om9602264

Reference yield: 99.0%

ethanol (64-17-5) + (CH3C(CH2P(C6H5)2)3)Re(CO)2(CCH2)(1+)*BF4(1-)=[(CH3C(CH2P(C6H5)2)3)Re(CO)2(CCH2)]BF4 (180320-96-1) → (CH3C(CH2P(C6H5)2)3)Re(CO)2(CC(CH3)OC2H5)(1+)*BF4(1-)=[(CH3C(CH2P(C6H5)2)3)Re(CO)2(CC(CH3)OC2H5)]BF4

Guidance literature:

In dichloromethane; N2-atmosphere; stirring (room temp., 2 h); crystn. on EtOH / Et2O (1 : 2) addn.; elem. anal.;

DOI:10.1021/om9602264

upstream raw materials:

(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(H)

tetrafluoroboric acid dimethyl ether complex

trimethylsilylacetylene

[(MeC(CH2PPh2)3)Re(CO)2(η(2)-H2)]BF4

Downstream raw materials:

(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(C(O)CH₃)

(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)][B(C₆H₅)4]

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 180320-96-1 (CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)⁽¹⁺⁾*BF₄^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CCH₂)]BF₄

Send

Send

Metric Ton KG G Pound L ML

Send

Send