1,2-Dihydrocyclopent[fg]acenaphthylene

Base Information

Chemical Name:1,2-Dihydrocyclopent[fg]acenaphthylene
CAS No.:23357-60-0
Molecular Formula:C₁₄H₁₀
Molecular Weight:178.233
Hs Code.:
DSSTox Substance ID:DTXSID401283704
Nikkaji Number:J773.142F

Synonyms:1,2-Dihydrocyclopent[fg]acenaphthylene;DTXSID401283704;23357-60-0

Suppliers and Price of 1,2-Dihydrocyclopent[fg]acenaphthylene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,2-Dihydrocyclopent[fg]acenaphthylene

Chemical Property:

XLogP3:4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:178.078250319
Heavy Atom Count:14
Complexity:252

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CC2=CC=C3C=CC4=C3C2=C1C=C4

Technology Process of 1,2-Dihydrocyclopent[fg]acenaphthylene

There total 1 articles about 1,2-Dihydrocyclopent[fg]acenaphthylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 177205-97-9
5-(1-chloroethenyl)acenaphthene

: 33918-41-1
5-ethynylacenaphthene

: 187-78-0
Pyracyclen

: 4-Vinylacenaphtylen

: 23357-60-0
1,2-dihydropyracylene

: 5-ethynylacenaphthylene

: 208-96-8,25036-01-5
acenaphthylene

Guidance literature:: at 900 ℃; under 0.01 Torr; Product distribution; Mechanism; var. temp., other acenaphthene and naphthalene derivatives;

Reference yield: 16.0%

: 6,7-dibromo-1,4-carbonylo-9,10-epoxy-1,2,3,4,5,8-hexaphenyl-1,4,4a,9,9a,10-hexahydroanthracene

: 23357-60-0
1,2-dihydropyracylene

: 1360548-22-6
exo-7,8-dibromo-5,10-epoxy-6,9-diphenyl-1,2,4b1,5,10,10a-hexahydrobenzo[k]cyclopenta[cd]fluoranthene

: 1360548-16-8
endo-7,8-dibromo-5,10-epoxy-6,9-diphenyl-1,2,4b1,5,10,10a-hexahydrobenzo[k]cyclopenta[cd]fluoranthene

Guidance literature:: In toluene; for 50h; Reflux;
DOI:10.1002/chem.201100443

Reference yield:

: 23357-60-0
1,2-dihydropyracylene

: endo-anti-4b,5,7,7a,8,11,11a,12,14,14a-decahydro-8,11-carbonyl-5,14:7,12-diepoxy-6,13-dihexyl-8,9,10,11-tetraphenylacenaphtheno[1',8':2,3,4]cyclopenta[1,2-b]naphthacene

Guidance literature:: Multi-step reaction with 4 steps

1: 8.61 g / toluene / 24 h / Heating

2: 85 percent / DDQ / toluene / 1.5 h / Heating

3: 930 mg / BuLi / toluene / 2 h / -30 °C

4: 67 percent / ethanol / 2 h / Heating

With n-butyllithium; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In ethanol; toluene; 1: Diels-Alder reaction / 4: Diels-Alder reaction;
DOI:10.1002/chem.200304824