rhodium(III) tetrakis(4-tolyl)porphyrin chloride

Base Information

• Chemical Name: rhodium(III) tetrakis(4-tolyl)porphyrin chloride
• CAS No.: 205259-72-9
• Molecular Formula: C₄₈H₃₆ClN₄Rh
• Molecular Weight: 807.199
• Mol file: 205259-72-9.mol

Synonyms:rhodium(III) tetrakis(4-tolyl)porphyrin chloride

Chemical Property of rhodium(III) tetrakis(4-tolyl)porphyrin chloride

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of rhodium(III) tetrakis(4-tolyl)porphyrin chloride

There total 6 articles about rhodium(III) tetrakis(4-tolyl)porphyrin chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

5,10,15,20-tetrakis(4-methylphenyl)porphyrin + rhodium(III) chloride trihydrate → rhodium(III) tetrakis(4-tolyl)porphyrin chloride (205259-72-9)

Guidance literature:

In benzonitrile; refluxing porphyrine with 2 equiv. of Rh-salt for 1 h; solvent removal (vac.), chromy. (SiO2, CHCl3);

DOI:10.1016/S0022-328X(98)00812-2

Reference yield: 76.0%

5,10,15,20-tetrakis(4-methylphenyl)porphyrin + rhodium(III) trichloride hydrate → rhodium(III) tetrakis(4-tolyl)porphyrin chloride (205259-72-9)

Guidance literature:

In benzonitrile; the mixt. in benzonitrile was refluxed in air for 3 h; the solvent was removed, column chromy. on silica gel (CH2Cl2), dried under vac. at 80°C, recrystd. from CH2Cl2/CH3OH;

DOI:10.1021/om0507878

Reference yield: 54.0%

di(rhodium)tetracarbonyl dichloride + 5,10,15,20-tetra(p-tolyl)porphyrin (14527-51-6) → rhodium(III) tetrakis(4-tolyl)porphyrin chloride (205259-72-9)

Guidance literature:

In toluene; for 6h; Inert atmosphere;

DOI:10.1021/ja411665k

upstream raw materials:

benzonitrile

5,10,15,20-tetra(p-tolyl)porphyrin

chlorobenzene

Downstream raw materials:

Rh(5,10,15,20-tetratolylporphyrinato)(β-aminoethyl)

(5,10,15,20-tetrakis-4-tolylporphyrinato)(methyl)rhodium(III)

(5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride

rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)Bn(4-tBu)