methyl (S)-2-(benzyloxycarbonylamino)-3-(3-formyl-4-hydroxyphenyl)propionate

Base Information

Chemical Name:methyl (S)-2-(benzyloxycarbonylamino)-3-(3-formyl-4-hydroxyphenyl)propionate
CAS No.:367967-64-4
Molecular Formula:C₁₉H₁₉NO₆
Molecular Weight:357.363
Hs Code.:

Synonyms:methyl (S)-2-(benzyloxycarbonylamino)-3-(3-formyl-4-hydroxyphenyl)propionate

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Chemical Property of methyl (S)-2-(benzyloxycarbonylamino)-3-(3-formyl-4-hydroxyphenyl)propionate

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Technology Process of methyl (S)-2-(benzyloxycarbonylamino)-3-(3-formyl-4-hydroxyphenyl)propionate

There total 5 articles about methyl (S)-2-(benzyloxycarbonylamino)-3-(3-formyl-4-hydroxyphenyl)propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 201230-82-2
carbon monoxide

: 79677-60-4
(S)-N-benzyloxycarbonyl-3-(4-hydroxy-3-iodophenyl)alanine methyl ester

: 367967-64-4
methyl (S)-2-(benzyloxycarbonylamino)-3-(3-formyl-4-hydroxyphenyl)propionate

Guidance literature:: With triethylsilane; 1,1'-bis-(diphenylphosphino)ferrocene; triethylamine; palladium diacetate; In N,N-dimethyl-formamide; at 80 ℃; for 3h;
DOI:10.1081/scc-100104476

Reference yield: 43.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 13512-31-7
N-(benzyloxycarbonyl)-L-tyrosine methyl ester

: 367967-64-4
methyl (S)-2-(benzyloxycarbonylamino)-3-(3-formyl-4-hydroxyphenyl)propionate

Guidance literature:: With triethylamine; magnesium chloride; In acetonitrile; for 18h; Reflux;
DOI:10.1016/j.bmcl.2009.04.081

Reference yield:

: 70-78-0
3-Iodo-L-tyrosine

: 367967-64-4
methyl (S)-2-(benzyloxycarbonylamino)-3-(3-formyl-4-hydroxyphenyl)propionate

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / HCl / 2 h / 0 °C

2: 89 percent / Na₂CO₃ / H₂O; diethyl ether / 3 h / 20 °C

3: 82 percent / dppf; Et₃N; Et₃SiH / Pd(OAc)2 / dimethylformamide / 3 h / 80 °C

With hydrogenchloride; triethylsilane; 1,1'-bis-(diphenylphosphino)ferrocene; sodium carbonate; triethylamine; palladium diacetate; In diethyl ether; water; N,N-dimethyl-formamide;
DOI:10.1081/scc-100104476