Cyclohexanamine, 1-ethenyl- (9CI)

Base Information

• Chemical Name: Cyclohexanamine, 1-ethenyl- (9CI)
• CAS No.: 111709-87-6
• Molecular Formula: C₈H₁₅N
• Molecular Weight: 125.214
• Mol file: 111709-87-6.mol

Synonyms:Cyclohexanamine, 1-ethenyl- (9CI)

Chemical Property of Cyclohexanamine, 1-ethenyl- (9CI)

Chemical Property:

• Boiling Point: 162.1±19.0 °C(Predicted)
• PKA: 9.74±0.70(Predicted)
• PSA: 26.02000
• Density: 0.939±0.06 g/cm3(Predicted)
• LogP: 2.53430

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclohexanamine, 1-ethenyl- (9CI)

There total 5 articles about Cyclohexanamine, 1-ethenyl- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Ethynylcyclohexylamine (30389-18-5) → 1-ethylcyclohexan-1-amine (2626-60-0) + amino-1 vinyl-1 cyclohexane (111709-87-6)

Guidance literature:

With hydrogen; In glycerol; at 100 ℃; for 24h; under 750.075 Torr;

DOI:10.1002/adsc.201800786

Reference yield:

2-methyl-N-(1-vinylcyclohexyl)propane-2-sulfinamide (1431851-25-0) → amino-1 vinyl-1 cyclohexane (111709-87-6)

Guidance literature:

With hydrogenchloride; In 1,4-dioxane; methanol; at 0 - 20 ℃; for 0.166667h; Inert atmosphere;

DOI:10.1021/ja4026787

Reference yield:

C14H18Cl6N2O4 → amino-1 vinyl-1 cyclohexane (111709-87-6)

Guidance literature:

With acetic acid; zinc; In acetone; Yield given; Ambient temperature; 1) 15 min 2) 1 h;

DOI:10.1021/jo00005a063

upstream raw materials:

ethylidenecyclohexane

2-methyl-N-(1-vinylcyclohexyl)propane-2-sulfinamide

N-cyclohexylidene-2-methylpropane-2-sulfinamide

1-Ethynylcyclohexylamine

Downstream raw materials:

1-acetamido-2-vinylcyclohexane

N-(1-Ethenylcyclohexyl)formamid

1-Ethenylcyclohexylcyanid

1-Ethenylcyclohexylisocyanid

Refernces

• 1、 Armanino, Nicolas,Carreira, Erick M.. "Ruthenium-catalyzed intramolecular hydrocarbamoylation of allylic formamides: Convenient access to chiral pyrrolidones". supporting information. p. 6814 - 6817. Retrieved 2013/06/05.