methyl α-phenyl-α-((phenyl(methoxycarbonyl)methylene)hydrazono)acetate

Base Information

• Chemical Name: methyl α-phenyl-α-((phenyl(methoxycarbonyl)methylene)hydrazono)acetate
• CAS No.: 72410-77-6
• Molecular Formula: C₁₈H₁₆N₂O₄
• Molecular Weight: 324.336
• Mol file: 72410-77-6.mol

Synonyms:methyl α-phenyl-α-((phenyl(methoxycarbonyl)methylene)hydrazono)acetate

Chemical Property of methyl α-phenyl-α-((phenyl(methoxycarbonyl)methylene)hydrazono)acetate

Chemical Property:

Purity/Quality:

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Technology Process of methyl α-phenyl-α-((phenyl(methoxycarbonyl)methylene)hydrazono)acetate

There total 14 articles about methyl α-phenyl-α-((phenyl(methoxycarbonyl)methylene)hydrazono)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Methyl phenyldiazoacetate (22979-35-7) → methyl α-phenyl-α-((phenyl(methoxycarbonyl)methylene)hydrazono)acetate (72410-77-6)

Guidance literature:

With (5,10,15,20-tetrakis(p-tolyl)porphyrinato)(methyl)iridium(III); In pentane; Inert atmosphere; Reflux;

DOI:10.1021/om3005433

Reference yield: 91.0%

Methyl phenyldiazoacetate (22979-35-7) + phenylmagnesium bromide (100-58-3) → biphenyl (92-52-4,1594-86-1) + methyl α-phenyl-α-((phenyl(methoxycarbonyl)methylene)hydrazono)acetate (72410-77-6)

Guidance literature:

With 1,1'-bis-(diphenylphosphino)ferrocene; copper dichloride; In tetrahydrofuran; at -15 ℃; for 6h; Inert atmosphere; Schlenk technique;

DOI:10.1002/aoc.6522

Reference yield: 74.0%

cyclohexane (110-82-7,25012-93-5) + Methyl phenyldiazoacetate (22979-35-7) → methyl 2-cyclohexyl-2-phenylacetate (13027-73-1) + methyl α-phenyl-α-((phenyl(methoxycarbonyl)methylene)hydrazono)acetate (72410-77-6)

Guidance literature:

With (5,10,15,20-tetrakis(p-tolyl)porphyrinato)(methyl)iridium(III); at 80 ℃; Inert atmosphere;

DOI:10.1021/om3005433

upstream raw materials:

methyl 2-oxo-2-phenylacetate

2,3-dimethylbutane

Methyl phenyldiazoacetate

copper(I) hexylacetylenide