1-chloro-1-mesityl-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)-silacycloheptatriene

Base Information

Chemical Name:1-chloro-1-mesityl-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)-silacycloheptatriene
CAS No.:303153-78-8
Molecular Formula:C₃₃H₄₁ClSi
Molecular Weight:501.227
Hs Code.:

Synonyms:1-chloro-1-mesityl-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)-silacycloheptatriene

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Chemical Property of 1-chloro-1-mesityl-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)-silacycloheptatriene

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Technology Process of 1-chloro-1-mesityl-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)-silacycloheptatriene

There total 3 articles about 1-chloro-1-mesityl-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)-silacycloheptatriene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 576-83-0
2,4,6-trimethylphenyl bromide

: 205128-81-0
1,1-dichloro-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)silacycloheptatriene

: 303153-78-8
1-chloro-1-mesityl-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)-silacycloheptatriene

Guidance literature:: 2,4,6-trimethylphenyl bromide; With tert.-butyl lithium; In tetrahydrofuran; pentane;

1,1-dichloro-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)silacycloheptatriene; In tetrahydrofuran; pentane; at 20 ℃; for 0.5h; Further stages.;
DOI:10.1021/ja0014685

Reference yield: 40.0%

: 5806-59-7
mesityllithium

: 205128-81-0
1,1-dichloro-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)silacycloheptatriene

: 303153-78-8
1-chloro-1-mesityl-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)-silacycloheptatriene

Guidance literature:: In tetrahydrofuran; at 20 ℃; for 0.5h;
DOI:10.1016/S0040-4020(01)00253-8

Reference yield:

: 112439-99-3
3,3''-Dibromo-[2,2';3',2'']ter[bicyclo[2.2.2]octane]-2,2',2''-triene

: 303153-78-8
1-chloro-1-mesityl-2,3:4,5:6,7-tris(bicyclo[2.2.2]octeno)-silacycloheptatriene

Guidance literature:: Multi-step reaction with 2 steps

1: 55 percent / t-BuLi; SiCl₄ / tetrahydrofuran; pentane / 0.75 h / -50 °C

2: 40 percent / tetrahydrofuran / 0.5 h / 20 °C

With tetrachlorosilane; tert.-butyl lithium; In tetrahydrofuran; pentane;
DOI:10.1016/S0040-4020(01)00253-8