1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium bromide

Base Information

• Chemical Name: 1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium bromide
• CAS No.: 1337917-55-1
• Molecular Formula: Br*C₂₂H₂₉N₂
• Molecular Weight: 401.39
• Mol file: 1337917-55-1.mol

Synonyms:1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium bromide

Chemical Property of 1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium bromide

There total 1 articles about 1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

1,5-dibromo-pentane (111-24-0) + N,N'-bis-2,6-xylylformamidine (16596-05-7) → 1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium bromide (1337917-55-1)

Guidance literature:

With potassium carbonate; In acetonitrile; Reflux;

DOI:10.1021/om200467x

Reference yield: 91.0%

1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium bromide (1337917-55-1) → 1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium tetrafluoroborate (1337917-57-3)

Guidance literature:

With sodium tetrafluoroborate; In water; acetone; at 20 ℃; for 0.333333h;

DOI:10.1021/om200467x

Reference yield: 91.0%

sodium tetrafluoroborate (13755-29-8) + 1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium bromide (1337917-55-1) → 1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium tetrafluoroborate (1337917-57-3)

Guidance literature:

In water; acetone; under Ar; Br-contg. compd. (0.5 mmol) in acetone and B-contg. compd. (0.6 mmol) in H2O were stirred together at room temp. for 20 min; acetone was evapd. at room temp.; the compd. was collected by filtration, dissolved in CH2Cl2 and dried iver MgSO4; after filtration, the solvent was concd. to ca. 2 mL and ether was added to the soln.;

DOI:10.1021/om200467x

upstream raw materials:

1,5-dibromo-pentane

N,N'-bis-2,6-xylylformamidine

Downstream raw materials:

[Ag(1,3-bis(2,6-dimethylphenyl)-1,3-diazocane-2-ylidene)Br]

1,3-bis(2,6-dimethylphenyl)-3,4,5,6,7,8-hexahydro-1,3-diazocin-1-ium tetrafluoroborate

C₂₂H₂₈N₂