trans-bis(triethylphosphino)⁽¹³⁾C-hydroxycarbonylphenyl platinum(II)

Base Information

Chemical Name:trans-bis(triethylphosphino)⁽¹³⁾C-hydroxycarbonylphenyl platinum(II)
CAS No.:115650-78-7
Molecular Formula:C₁₉H₃₆O₂P₂Pt
Molecular Weight:554.51
Hs Code.:

trans-bis(triethylphosphino)<sup>(13)</sup>C-hydroxycarbonylphenyl platinum(II)

Synonyms:trans-bis(triethylphosphino)⁽¹³⁾C-hydroxycarbonylphenyl platinum(II)

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Chemical Property of trans-bis(triethylphosphino)⁽¹³⁾C-hydroxycarbonylphenyl platinum(II)

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Technology Process of trans-bis(triethylphosphino)⁽¹³⁾C-hydroxycarbonylphenyl platinum(II)

There total 1 articles about trans-bis(triethylphosphino)⁽¹³⁾C-hydroxycarbonylphenyl platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 76124-93-1
trans-bis(triethylphosphine)(hydroxy)(phenyl)platinum(II)

: 1641-69-6
[13C]Carbon monoxide

: 115650-78-7
trans-bis(triethylphosphino)⁽¹³⁾C-hydroxycarbonylphenyl platinum(II)

Guidance literature:: In further solvent(s); soln. of Pt complex in isopentane was stirred under (13)CO (slightly above atmosphere pressure) for 10 min at room temp., white solid formed; solvent was reduced to ca. 1 ml in vac.; solid removed by centrifugation, washed with cold isopentane and dried in vac.; elem. anal.;
DOI:10.1021/ja00229a024

Reference yield: 90.0%

: 115650-78-7
trans-bis(triethylphosphino)⁽¹³⁾C-hydroxycarbonylphenyl platinum(II)

: 115650-86-7
(C6H5)(Et3P)2Pt(μ-(13)CO2)Pt(C6H5)(Et3P)2

Guidance literature:: In neat (no solvent); byproducts: (13)CO; thermal decompn. at 60-100°C (oil bath) in N2-stream, extn. of residue with isopentane, removal of solvent in vac.; elem. anal.;
DOI:10.1021/ja00229a024

Reference yield: 76.0%

: 115650-78-7
trans-bis(triethylphosphino)⁽¹³⁾C-hydroxycarbonylphenyl platinum(II)

: 115650-83-4
trans-bis(triethylphosphino)methoxy-⁽¹³⁾C-carbonylphenyl platinum(II)

Guidance literature:: With CH₃OH; In methanol; soln. of Pt complex in MeOH was held at room temp. for 2 h, then solvent was removed under reduced pressure; residue was washed with isopentane and dried in vac.; elem. anal.;
DOI:10.1021/ja00229a024