2-furan-(phenyl)iodonium tosylate

Base Information

• Chemical Name: 2-furan-(phenyl)iodonium tosylate
• CAS No.: 85925-49-1
• Molecular Formula: C₇H₇O₃S*C₁₀H₈IO
• Molecular Weight: 442.274
• Mol file: 85925-49-1.mol

Synonyms:2-furan-(phenyl)iodonium tosylate

Chemical Property of 2-furan-(phenyl)iodonium tosylate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 2-furan-(phenyl)iodonium tosylate

There total 2 articles about 2-furan-(phenyl)iodonium tosylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

fur-2-ylboronic acid (13331-23-2) + [hydroxy(tosyloxy)iodo]benzene (27126-76-7) → 2-furan-(phenyl)iodonium tosylate (85925-49-1)

Guidance literature:

In dichloromethane; at 20 ℃;

DOI:10.1016/S0040-4039(00)00861-3

Reference yield: 20.0%

2-furyltrimethylsilane (1578-33-2) + [hydroxy(tosyloxy)iodo]benzene (27126-76-7) → 2-furan-(phenyl)iodonium tosylate (85925-49-1)

Guidance literature:

In methanol; for 48h; Ambient temperature;

DOI:10.1021/jo00163a022

Reference yield: 41.0%

5-(1-(tert-butyldimethylsilyloxy)-7-phenylheptyl)-2H-tetrazole (1042153-35-4) + 2-furan-(phenyl)iodonium tosylate (85925-49-1) → 5-(1-(tert-butyldimethylsilyloxy)-7-phenylheptyl)-2-(furan-2-yl)-2H-tetrazole (1042153-39-8)

Guidance literature:

With copper diacetate; triethylamine; In dichloromethane; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1021/jm800136b

upstream raw materials:

2-furyltrimethylsilane

[hydroxy(tosyloxy)iodo]benzene

fur-2-ylboronic acid

Downstream raw materials:

fluorobenzene

5-(1-(tert-butyldimethylsilyloxy)-7-phenylheptyl)-2-(furan-2-yl)-2H-tetrazole

Refernces

• 1、 Carman, Carol S.,Koser, Gerald F.. "Regiospecific Synthesis of Aryl(2-furyl)iodonium Tosylates, a New Class of Iodonium Salts, from arenes and 2-(Trimethylsilyl)furans in Organic Solvents". . p. 2534 - 2539. Retrieved 2007/10/02.