3-benzyloxy-4-[1,1,4-trioxo-5-(2-trimethylsilanyl-ethyl)-1,2,5-thiadiazolidin-2-yl]-benzaldehyde

Base Information

Chemical Name:3-benzyloxy-4-[1,1,4-trioxo-5-(2-trimethylsilanyl-ethyl)-1,2,5-thiadiazolidin-2-yl]-benzaldehyde
CAS No.:941594-23-6
Molecular Formula:C₂₁H₂₆N₂O₅SSi
Molecular Weight:446.599
Hs Code.:

Synonyms:3-benzyloxy-4-[1,1,4-trioxo-5-(2-trimethylsilanyl-ethyl)-1,2,5-thiadiazolidin-2-yl]-benzaldehyde

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Chemical Property of 3-benzyloxy-4-[1,1,4-trioxo-5-(2-trimethylsilanyl-ethyl)-1,2,5-thiadiazolidin-2-yl]-benzaldehyde

Chemical Property:

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Technology Process of 3-benzyloxy-4-[1,1,4-trioxo-5-(2-trimethylsilanyl-ethyl)-1,2,5-thiadiazolidin-2-yl]-benzaldehyde

There total 10 articles about 3-benzyloxy-4-[1,1,4-trioxo-5-(2-trimethylsilanyl-ethyl)-1,2,5-thiadiazolidin-2-yl]-benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 941594-21-4
5-(2-benzyloxy-4-vinylphenyl)-1,1-dioxo-2-(2-trimethylsilanyl-ethyl)-1,2,5-thiadiazolidin-3-one

: 941594-23-6
3-benzyloxy-4-[1,1,4-trioxo-5-(2-trimethylsilanyl-ethyl)-1,2,5-thiadiazolidin-2-yl]-benzaldehyde

Guidance literature:: 5-(2-benzyloxy-4-vinylphenyl)-1,1-dioxo-2-(2-trimethylsilanyl-ethyl)-1,2,5-thiadiazolidin-3-one; With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In tetrahydrofuran; water; tert-butyl alcohol; at 20 ℃; for 4h;

With sodium periodate; sodium hydrogencarbonate; In tetrahydrofuran; water; tert-butyl alcohol; for 1h;

Reference yield:

: 1057341-60-2
2-benzyloxy-4-iodophenylamine

: 941594-23-6
3-benzyloxy-4-[1,1,4-trioxo-5-(2-trimethylsilanyl-ethyl)-1,2,5-thiadiazolidin-2-yl]-benzaldehyde

Guidance literature:: Multi-step reaction with 7 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 4 h / 50 °C

2.1: dichloromethane / 0 °C

2.2: 0.5 h / 0 °C

3.1: di-isopropyl azodicarboxylate; triphenylphosphine / toluene / 19 h

4.1: trifluoroacetic acid / dichloromethane / 2 h / 20 °C

5.1: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / tetrahydrofuran / 3 h / 20 °C

6.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tris-(o-tolyl)phosphine / acetonitrile / 18 h / 80 °C

6.2: 0.25 h

7.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / tetrahydrofuran; water; tert-butyl alcohol / 4 h / 20 °C

7.2: 1 h

With osmium(VIII) oxide; di-isopropyl azodicarboxylate; potassium carbonate; benzotriazol-1-ol; 4-methylmorpholine N-oxide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; triphenylphosphine; trifluoroacetic acid; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tris-(o-tolyl)phosphine; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; tert-butyl alcohol;

Reference yield:

: 1057340-17-6
2-benzyloxy-4-iodo-1-nitrobenzene

: 941594-23-6
3-benzyloxy-4-[1,1,4-trioxo-5-(2-trimethylsilanyl-ethyl)-1,2,5-thiadiazolidin-2-yl]-benzaldehyde

Guidance literature:: Multi-step reaction with 8 steps

1.1: iron; acetic acid / ethanol / 1.5 h / 100 °C / Heating / reflux

2.1: potassium carbonate / N,N-dimethyl-formamide / 4 h / 50 °C

3.1: dichloromethane / 0 °C

3.2: 0.5 h / 0 °C

4.1: di-isopropyl azodicarboxylate; triphenylphosphine / toluene / 19 h

5.1: trifluoroacetic acid / dichloromethane / 2 h / 20 °C

6.1: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / tetrahydrofuran / 3 h / 20 °C

7.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tris-(o-tolyl)phosphine / acetonitrile / 18 h / 80 °C

7.2: 0.25 h

8.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / tetrahydrofuran; water; tert-butyl alcohol / 4 h / 20 °C

8.2: 1 h

With osmium(VIII) oxide; di-isopropyl azodicarboxylate; iron; potassium carbonate; benzotriazol-1-ol; acetic acid; 4-methylmorpholine N-oxide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; triphenylphosphine; trifluoroacetic acid; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tris-(o-tolyl)phosphine; In tetrahydrofuran; ethanol; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; tert-butyl alcohol;