{Ru(III)(bis(salicylaldehyde)-o-phenylenediamine^(2-))(2-methylimidazole)Cl}

Base Information

Chemical Name:{Ru(III)(bis(salicylaldehyde)-o-phenylenediamine^(2-))(2-methylimidazole)Cl}
CAS No.:114286-67-8
Molecular Formula:C₂₄H₂₀ClN₄O₂Ru
Molecular Weight:532.971
Hs Code.:

{Ru(III)(bis(salicylaldehyde)-o-phenylenediamine<sup>(2-)</sup>)(2-methylimidazole)Cl}

Synonyms:{Ru(III)(bis(salicylaldehyde)-o-phenylenediamine^(2-))(2-methylimidazole)Cl}

Suppliers and Price of {Ru(III)(bis(salicylaldehyde)-o-phenylenediamine^(2-))(2-methylimidazole)Cl}

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {Ru(III)(bis(salicylaldehyde)-o-phenylenediamine^(2-))(2-methylimidazole)Cl}

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of {Ru(III)(bis(salicylaldehyde)-o-phenylenediamine^(2-))(2-methylimidazole)Cl}

There total 1 articles about {Ru(III)(bis(salicylaldehyde)-o-phenylenediamine^(2-))(2-methylimidazole)Cl} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 693-98-1
2-methylimidazole

: potassium aquapentachlororuthenate(III)

: 3946-91-6
N,N'-bis(salicylidene)-o-phenylenediamine

: 114286-67-8
{chloro-2-methylimidazolebis(salicylaldehyde)-o-phenylenediiminatoruthenate(III)}

Guidance literature:: In ethanol; byproducts: KCl; refluxing for 15 h under dry Ar, then addn. of 2-methylimidazole, refluxing for 8 h; filtration of KCl, concn. of filtrate, addn. of diethyl ether, pptn., elem. anal.;
DOI:10.1016/0304-5102(88)80082-8

Reference yield:

: 114286-67-8
{Ru(III)(bis(salicylaldehyde)-o-phenylenediamine^(2-))(2-methylimidazole)Cl}

: 536-80-1
iodosylbenzene

: 591-50-4
iodobenzene

: {Ru(V)(bis(salicylaldehyde)-o-phenylenediamine^(2-))(2-methylimidazole)(O)}Cl

Guidance literature:: In 1,4-dioxane; water; N,N-dimethyl-formamide; in 1:1 water-dioxane/DMF, addn. of iodosylbenzene, stirred for 6 h; extn. of iodobenzene (diethyl ether), evapd. almost to dryness, addn. of ether; elem. anal.;
DOI:10.1016/S0020-1693(00)85173-7

Reference yield:

: 114286-67-8
{chloro-2-methylimidazolebis(salicylaldehyde)-o-phenylenediiminatoruthenate(III)}

: 80937-33-3
oxygen

: Ru⁽⁴⁺⁾*(OC₆H₄CHNC₆H₄NCHC₆H₄O)^(2-)*(C₃H₃N₂(CH₃))*O₂^(1-)

Guidance literature:: In 1,4-dioxane; water; reaction for 3 h in 50% v/v water-dioxane, then bubbling of O2 through the reaction mixt. at various pressures (0.2-1.0 atm); rate of oxygenation measured manometrically; Kinetics;
DOI:10.1016/0304-5102(88)80082-8