Acetic acid (2aS,6R,7R,7aS,7bR)-6-isopropyl-1,7b-dimethyl-4-oxo-4a-phenylselanyl-decahydro-cyclopenta[cd]indol-7-yl ester

Base Information

Chemical Name:Acetic acid (2aS,6R,7R,7aS,7bR)-6-isopropyl-1,7b-dimethyl-4-oxo-4a-phenylselanyl-decahydro-cyclopenta[cd]indol-7-yl ester
CAS No.:345665-15-8
Molecular Formula:C₂₃H₃₁NO₃Se
Molecular Weight:448.464
Hs Code.:

Synonyms:Acetic acid (2aS,6R,7R,7aS,7bR)-6-isopropyl-1,7b-dimethyl-4-oxo-4a-phenylselanyl-decahydro-cyclopenta[cd]indol-7-yl ester

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Chemical Property of Acetic acid (2aS,6R,7R,7aS,7bR)-6-isopropyl-1,7b-dimethyl-4-oxo-4a-phenylselanyl-decahydro-cyclopenta[cd]indol-7-yl ester

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Technology Process of Acetic acid (2aS,6R,7R,7aS,7bR)-6-isopropyl-1,7b-dimethyl-4-oxo-4a-phenylselanyl-decahydro-cyclopenta[cd]indol-7-yl ester

There total 8 articles about Acetic acid (2aS,6R,7R,7aS,7bR)-6-isopropyl-1,7b-dimethyl-4-oxo-4a-phenylselanyl-decahydro-cyclopenta[cd]indol-7-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₂H₁₉NO₃

: 345665-15-8
Acetic acid (2aS,6R,7R,7aS,7bR)-6-isopropyl-1,7b-dimethyl-4-oxo-4a-phenylselanyl-decahydro-cyclopenta[cd]indol-7-yl ester

Guidance literature:: Multi-step reaction with 9 steps

1: Et₃N

2: 71 percent / Bu₃SnH, AIBN / toluene / Heating

3: 68 percent / aq. KOH / ethanol

4: K₂CO₃

5: pyridine

6: 2.) N-methylmorpholine oxide hydrate / 2.) CH₃CN

7: H₂ / Pd/C

8: HMDS / CH₂Cl₂ / -20 °C

With pyridine; potassium hydroxide; 2,2'-azobis(isobutyronitrile); hydrogen; tri-n-butyl-tin hydride; potassium carbonate; 4-methylmorpholine N-oxide; triethylamine; 1,1,1,3,3,3-hexamethyl-disilazane; palladium on activated charcoal; In ethanol; dichloromethane; toluene;
DOI:10.1021/ja990707p

Reference yield:

: 242130-24-1
(+)-(1R,2S,6R)-6-isopropyl-3-methyl-2-methylamino-cyclohex-3-enol

: 345665-15-8
Acetic acid (2aS,6R,7R,7aS,7bR)-6-isopropyl-1,7b-dimethyl-4-oxo-4a-phenylselanyl-decahydro-cyclopenta[cd]indol-7-yl ester

Guidance literature:: Multi-step reaction with 6 steps

1: K₂CO₃

2: pyridine

3: 2.) N-methylmorpholine oxide hydrate / 2.) CH₃CN

4: H₂ / Pd/C

5: HMDS / CH₂Cl₂ / -20 °C

With pyridine; hydrogen; potassium carbonate; 4-methylmorpholine N-oxide; 1,1,1,3,3,3-hexamethyl-disilazane; palladium on activated charcoal; In dichloromethane;
DOI:10.1021/ja990707p

Reference yield:

: (1R,2S,6R)-6-Isopropyl-3-methyl-2-(methyl-prop-2-ynyl-amino)-cyclohex-3-enol

: 345665-15-8
Acetic acid (2aS,6R,7R,7aS,7bR)-6-isopropyl-1,7b-dimethyl-4-oxo-4a-phenylselanyl-decahydro-cyclopenta[cd]indol-7-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: pyridine

2: 2.) N-methylmorpholine oxide hydrate / 2.) CH₃CN

3: H₂ / Pd/C

4: HMDS / CH₂Cl₂ / -20 °C

With pyridine; hydrogen; 4-methylmorpholine N-oxide; 1,1,1,3,3,3-hexamethyl-disilazane; palladium on activated charcoal; In dichloromethane;
DOI:10.1021/ja990707p