11-cis-tert-butyldiphenylsilyl 11-fluororetinyl ether

Base Information

Chemical Name:11-cis-tert-butyldiphenylsilyl 11-fluororetinyl ether
CAS No.:186953-36-6
Molecular Formula:C₃₆H₄₇FOSi
Molecular Weight:542.852
Hs Code.:

Synonyms:11-cis-tert-butyldiphenylsilyl 11-fluororetinyl ether

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Chemical Property of 11-cis-tert-butyldiphenylsilyl 11-fluororetinyl ether

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Technology Process of 11-cis-tert-butyldiphenylsilyl 11-fluororetinyl ether

There total 4 articles about 11-cis-tert-butyldiphenylsilyl 11-fluororetinyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 186953-23-1
(E)-4-((tert-butyldiphenylsilyl)oxy)-2-methylbut-2-enal

: 186953-36-6
11-cis-tert-butyldiphenylsilyl 11-fluororetinyl ether

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 2.) THF, hexane, -78 deg C, 25 deg C (3 h)

2: 90 percent / DIBALH / tetrahydrofuran; hexane / 1 h / 0 °C

3: 90 percent / BaMnO₄ / CH₂Cl₂ / 12 h / 25 °C

4: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 2.) THF, hexane, -78 deg C , 25 deg C (5 h)

With n-butyllithium; barium permanganate; diisobutylaluminium hydride; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo961355x

Reference yield:

: 186953-25-3
(2E,4E)-6-[(tert-butyldiphenylsilyl)oxy]-2-fluoro-4-methylhexa-2,4-dien-1-ol

: 186953-36-6
11-cis-tert-butyldiphenylsilyl 11-fluororetinyl ether

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / BaMnO₄ / CH₂Cl₂ / 12 h / 25 °C

2: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 2.) THF, hexane, -78 deg C , 25 deg C (5 h)

With n-butyllithium; barium permanganate; In dichloromethane;
DOI:10.1021/jo961355x

Reference yield:

: 186953-24-2
ethyl (2E,4E)-6-[(tert-butyldiphenylsilyl)oxy]-2-fluoro-4-methylhexa-2,4-dienoate

: 186953-36-6
11-cis-tert-butyldiphenylsilyl 11-fluororetinyl ether

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / DIBALH / tetrahydrofuran; hexane / 1 h / 0 °C

2: 90 percent / BaMnO₄ / CH₂Cl₂ / 12 h / 25 °C

3: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 2.) THF, hexane, -78 deg C , 25 deg C (5 h)

With n-butyllithium; barium permanganate; diisobutylaluminium hydride; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo961355x