trifluoro-methanesulfonic acid 6-benzyl-2-methylsulfanyl-cyclohex-1-enyl ester

Base Information

• Chemical Name: trifluoro-methanesulfonic acid 6-benzyl-2-methylsulfanyl-cyclohex-1-enyl ester
• CAS No.: 412909-80-9
• Molecular Formula: C₁₅H₁₇F₃O₃S₂
• Molecular Weight: 366.425
• Mol file: 412909-80-9.mol

Synonyms:trifluoro-methanesulfonic acid 6-benzyl-2-methylsulfanyl-cyclohex-1-enyl ester

Chemical Property of trifluoro-methanesulfonic acid 6-benzyl-2-methylsulfanyl-cyclohex-1-enyl ester

Chemical Property:

Purity/Quality:

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Technology Process of trifluoro-methanesulfonic acid 6-benzyl-2-methylsulfanyl-cyclohex-1-enyl ester

There total 1 articles about trifluoro-methanesulfonic acid 6-benzyl-2-methylsulfanyl-cyclohex-1-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

N,N-phenylbistrifluoromethane-sulfonimide (37595-74-7) + 2-benzyl-6-(methylthio)cyclohexanone → trifluoro-methanesulfonic acid 6-benzyl-2-methylsulfanyl-cyclohex-1-enyl ester (412909-80-9)

Guidance literature:

2-benzyl-6-(methylthio)cyclohexanone; With potassium hexamethylsilazane; In tetrahydrofuran; at -78 ℃; for 0.333333h;

N,N-phenylbistrifluoromethane-sulfonimide; In tetrahydrofuran; at -78 ℃; for 0.333333h; Further stages.;

DOI:10.1021/ol017303y

Reference yield: 89.0%

trifluoro-methanesulfonic acid 6-benzyl-2-methylsulfanyl-cyclohex-1-enyl ester (412909-80-9) → 6-benzyl-2-methylsulfanyl-cyclohex-2-enone

Guidance literature:

With 2,6-dimethylpyridine; In dimethyl sulfoxide; at 80 ℃; for 6h;

DOI:10.1021/ol017303y

upstream raw materials:

N,N-phenylbistrifluoromethane-sulfonimide