(E)-dimethyl(phenyl)(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-ene-2-yl)silane

Base Information

Chemical Name:(E)-dimethyl(phenyl)(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-ene-2-yl)silane
CAS No.:1187817-03-3
Molecular Formula:C₁₈H₂₉BO₂Si
Molecular Weight:316.324
Hs Code.:

Synonyms:(E)-dimethyl(phenyl)(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-ene-2-yl)silane

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Chemical Property of (E)-dimethyl(phenyl)(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-ene-2-yl)silane

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Technology Process of (E)-dimethyl(phenyl)(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-ene-2-yl)silane

There total 3 articles about (E)-dimethyl(phenyl)(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-ene-2-yl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 103223-44-5
(buta-1,3-dien-2-yl)dimethyl(phenyl)silane

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1187817-03-3
(E)-dimethyl(phenyl)(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-ene-2-yl)silane

Guidance literature:: With (E)-1,1-bis(3,5-dimethylphenyl)-N-(pyridin-2-ylmethylene)methanamine iron(II) chloride dichloromethane solvate; magnesium; 2,3-dimethyl-buta-1,3-diene; In diethyl ether; at 23 ℃; for 3.5h; regioselective reaction; Inert atmosphere;
DOI:10.1021/ja9048493

Reference yield: 87.0%

: 103223-44-5
(buta-1,3-dien-2-yl)dimethyl(phenyl)silane

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: B(OC(CH₃)2)2CH₂CCHCH₃Si(CH₃)2C₆H₅

: 1187817-03-3
(E)-dimethyl(phenyl)(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-ene-2-yl)silane

Guidance literature:: In dichloromethane; (N2) soln. diphosphene in CH2Cl2 was added dropwise to soln. Au complex in CH2Cl2 (1:2), stirred for 1 h; solvent was evapd., residue was triturated with pentane and dried; elem.anal.;
DOI:10.1021/ja900813v

Reference yield:

: 252639-93-3
(buta-2,3-dien-2-yl)dimethyl(phenyl)silane

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1187817-03-3
(E)-dimethyl(phenyl)(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)but-2-ene-2-yl)silane

: (Z)-2-(3-(dimethylphenylsilyl)but-2-enyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With C₂₈H₄₃Cl₂CoN₂P; sodium triethylborohydride; In tetrahydrofuran; toluene; at 50 ℃; for 48h; Overall yield = 69percent; Overall yield = 109.1 mg; stereoselective reaction; Inert atmosphere; Schlenk technique; Glovebox;
DOI:10.1002/anie.201915716