methyl (E)-3-(trans-2-phenylcyclopropyl)propenoate

Base Information

Chemical Name:methyl (E)-3-(trans-2-phenylcyclopropyl)propenoate
CAS No.:73765-25-0
Molecular Formula:C₁₃H₁₄O₂
Molecular Weight:202.253
Hs Code.:

Synonyms:methyl (E)-3-(trans-2-phenylcyclopropyl)propenoate

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Chemical Property of methyl (E)-3-(trans-2-phenylcyclopropyl)propenoate

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Technology Process of methyl (E)-3-(trans-2-phenylcyclopropyl)propenoate

There total 6 articles about methyl (E)-3-(trans-2-phenylcyclopropyl)propenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 1067-74-9
Methyl diethylphosphonoacetate

: 34271-31-3
trans-2-phenylcyclopropanecarbaldehyde

: 73765-25-0
methyl (E)-3-(trans-2-phenylcyclopropyl)propenoate

Guidance literature:: Methyl diethylphosphonoacetate; With sodium hydride; In mineral oil; benzene; at 20 ℃; for 0.5h; Inert atmosphere;

trans-2-phenylcyclopropanecarbaldehyde; In mineral oil; benzene; for 0.5h;
DOI:10.1021/ol201112a

Reference yield:

: 939-90-2
trans-2-phenylcyclopropane-1-carboxylic acid

: 73765-25-0
methyl (E)-3-(trans-2-phenylcyclopropyl)propenoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: lithium aluminium tetrahydride / diethyl ether / 2 h / 0 - 20 °C / Inert atmosphere

1.2: 20 °C

2.1: pyridinium chlorochromate / dichloromethane / 20 °C / Inert atmosphere

3.1: sodium hydride / mineral oil; benzene / 0.5 h / 20 °C / Inert atmosphere

3.2: 0.5 h

With lithium aluminium tetrahydride; sodium hydride; pyridinium chlorochromate; In diethyl ether; dichloromethane; mineral oil; benzene; 3.2: Horner-Wadsworth-Emmons olefination;
DOI:10.1021/ol201112a

Reference yield:

: 79981-48-9
trans-(3-phenylcyclopropyl)methanol

: 73765-25-0
methyl (E)-3-(trans-2-phenylcyclopropyl)propenoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: pyridinium chlorochromate / dichloromethane / 20 °C / Inert atmosphere

2.1: sodium hydride / mineral oil; benzene / 0.5 h / 20 °C / Inert atmosphere

2.2: 0.5 h

With sodium hydride; pyridinium chlorochromate; In dichloromethane; mineral oil; benzene; 2.2: Horner-Wadsworth-Emmons olefination;
DOI:10.1021/ol201112a