Benzyloxycarbonylamino-acetic acid (E)-(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-2-enyl ester

Base Information

Chemical Name:Benzyloxycarbonylamino-acetic acid (E)-(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-2-enyl ester
CAS No.:215038-66-7
Molecular Formula:C₂₂H₃₁NO₆
Molecular Weight:405.491
Hs Code.:

Synonyms:Benzyloxycarbonylamino-acetic acid (E)-(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-2-enyl ester

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Chemical Property of Benzyloxycarbonylamino-acetic acid (E)-(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-2-enyl ester

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Technology Process of Benzyloxycarbonylamino-acetic acid (E)-(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-2-enyl ester

There total 1 articles about Benzyloxycarbonylamino-acetic acid (E)-(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1138-80-3
N-(Benzyloxycarbonyl)glycine

: 140381-97-1
(E)-(1S,4'R)-1-(2,2-dimethyl-1,3-dioxolane-4-yl)-hept-2-en-1-ol

: 215038-66-7
Benzyloxycarbonylamino-acetic acid (E)-(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-2-enyl ester

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; Ambient temperature;
DOI:10.1055/s-1998-6104

Reference yield:

: 215038-66-7
Benzyloxycarbonylamino-acetic acid (E)-(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-2-enyl ester

: (R)-2-Benzyloxycarbonylamino-3-[(E)-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-vinyl]-heptanoic acid

Guidance literature:: With zinc(II) chloride; lithium diisopropyl amide; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1055/s-1998-6104

Reference yield:

: 215038-66-7
Benzyloxycarbonylamino-acetic acid (E)-(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hept-2-enyl ester

: (R)-2-Benzyloxycarbonylamino-3-[(E)-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-vinyl]-heptanoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: LDA, ZnCl₂ / tetrahydrofuran / -78 - 20 °C

2: diethyl ether

With zinc(II) chloride; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether;
DOI:10.1055/s-1998-6104