1-[tert-butyl(diphenyl)silyloxy]-9-(triphenylsilyloxy)nonane

Base Information

• Chemical Name: 1-[tert-butyl(diphenyl)silyloxy]-9-(triphenylsilyloxy)nonane
• CAS No.: 862249-30-7
• Molecular Formula: C₄₃H₅₂O₂Si₂
• Molecular Weight: 657.056
• Mol file: 862249-30-7.mol

Synonyms:1-[tert-butyl(diphenyl)silyloxy]-9-(triphenylsilyloxy)nonane

Chemical Property of 1-[tert-butyl(diphenyl)silyloxy]-9-(triphenylsilyloxy)nonane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-[tert-butyl(diphenyl)silyloxy]-9-(triphenylsilyloxy)nonane

There total 3 articles about 1-[tert-butyl(diphenyl)silyloxy]-9-(triphenylsilyloxy)nonane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

1,9-Nonanediol (3937-56-2) + Triphenylsilyl chloride (76-86-8) + tert-butylchlorodiphenylsilane (58479-61-1) → 1-[tert-butyl(diphenyl)silyloxy]-9-(triphenylsilyloxy)nonane (862249-30-7)

Guidance literature:

1,9-Nonanediol; Triphenylsilyl chloride; With dmap; triethylamine; In dichloromethane; at 20 ℃;

tert-butylchlorodiphenylsilane; With dmap; triethylamine; In dichloromethane;

DOI:10.1016/j.tet.2005.03.145

Reference yield:

1-[dimethyl(phenyl)silyloxy]-9-(triphenylsilyloxy)nonane (862249-29-4) → 1-[tert-butyl(diphenyl)silyloxy]-9-(triphenylsilyloxy)nonane (862249-30-7)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 79 percent / lithium; naphthalene / tetrahydrofuran; methanol / 3 h / 20 °C

2.1: triethylamine; 4-(dimethylamino)pyridine / CH₂Cl₂ / 20 °C

2.2: 73 percent / triethylamine; 4-(dimethylamino)pyridine / CH₂Cl₂

With dmap; naphthalene; lithium; triethylamine; In tetrahydrofuran; methanol; dichloromethane;

DOI:10.1016/j.tet.2005.03.145

Reference yield:

1,9-Nonanediol (3937-56-2) → 1-[tert-butyl(diphenyl)silyloxy]-9-(triphenylsilyloxy)nonane (862249-30-7)

Guidance literature:

Multi-step reaction with 3 steps

1.1: triethylamine; 4-(dimethylamino)pyridine / CH₂Cl₂ / 20 °C

1.2: 56 percent / triethylamine; 4-(dimethylamino)pyridine / CH₂Cl₂

2.1: 79 percent / lithium; naphthalene / tetrahydrofuran; methanol / 3 h / 20 °C

3.1: triethylamine; 4-(dimethylamino)pyridine / CH₂Cl₂ / 20 °C

3.2: 73 percent / triethylamine; 4-(dimethylamino)pyridine / CH₂Cl₂

With dmap; naphthalene; lithium; triethylamine; In tetrahydrofuran; methanol; dichloromethane;

DOI:10.1016/j.tet.2005.03.145

upstream raw materials:

1,9-Nonanediol

Triphenylsilyl chloride

tert-butylchlorodiphenylsilane

1-[dimethyl(phenyl)silyloxy]-9-(triphenylsilyloxy)nonane

Downstream raw materials:

9-(triphenylsilyloxy)-1-nonanol