methyl 3-benzyloxy-5-tert-butyldiphenylsilyloxybenzoate

Base Information

Chemical Name:methyl 3-benzyloxy-5-tert-butyldiphenylsilyloxybenzoate
CAS No.:271580-85-9
Molecular Formula:C₃₁H₃₂O₄Si
Molecular Weight:496.678
Hs Code.:

Synonyms:methyl 3-benzyloxy-5-tert-butyldiphenylsilyloxybenzoate

Suppliers and Price of methyl 3-benzyloxy-5-tert-butyldiphenylsilyloxybenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 3-benzyloxy-5-tert-butyldiphenylsilyloxybenzoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 3-benzyloxy-5-tert-butyldiphenylsilyloxybenzoate

There total 1 articles about methyl 3-benzyloxy-5-tert-butyldiphenylsilyloxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 54915-31-0
methyl 3-(benzyloxy)-5-hydroxybenzoate

: 58479-61-1
tert-butylchlorodiphenylsilane

: 271580-85-9
methyl 3-benzyloxy-5-tert-butyldiphenylsilyloxybenzoate

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃;
DOI:10.1016/S0040-4020(00)00078-8

Reference yield: 27.0%

: 271580-85-9
methyl 3-benzyloxy-5-tert-butyldiphenylsilyloxybenzoate

: 271580-86-0
3-benzyloxy-5-tert-butyldiphenylsilyloxybenzyl alcohol

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; for 1h; Heating;
DOI:10.1016/S0040-4020(00)00078-8

Reference yield:

: 271580-85-9
methyl 3-benzyloxy-5-tert-butyldiphenylsilyloxybenzoate

: (+/-)-2-(3-hydroxy-5-ethoxycarbonylmethoxybenzyl)-3-(3'-hydroxybenzyl)butyrolactone

Guidance literature:: Multi-step reaction with 6 steps

1.1: 27 percent / LiAlH₄ / diethyl ether / 1 h / Heating

2.1: 89 percent / PBr₃ / diethyl ether / 4 °C

3.1: n-BuLi / tetrahydrofuran / -78 °C

3.2: tetrahydrofuran / -78 °C

3.3: 18 percent / HMPA / tetrahydrofuran / -78 - 20 °C

4.1: 99 percent / TBAF / tetrahydrofuran / 20 °C

5.1: 99 percent / K₂CO₃; KI / acetone / Heating

6.1: 38 percent / Raney nickel / ethanol / Heating

With lithium aluminium tetrahydride; n-butyllithium; tetrabutyl ammonium fluoride; phosphorus tribromide; nickel; potassium carbonate; potassium iodide; In tetrahydrofuran; diethyl ether; ethanol; acetone; 1.1: Reduction / 2.1: Substitution / 3.1: Metallation / 3.2: Michael addition / 3.3: Benzylation / 4.1: Desilylation / 5.1: Substitution / 6.1: Reduction;
DOI:10.1016/S0040-4020(00)00078-8