6-Acetyl-2-isopropylnaphthalene

Base Information

• Chemical Name: 6-Acetyl-2-isopropylnaphthalene
• CAS No.: 107208-69-5
• Molecular Formula: C15H16 O
• Molecular Weight: 212.291
• DSSTox Substance ID: DTXSID70549350
• Nikkaji Number: J1.305.839C
• Wikidata: Q82428374
• Mol file: 107208-69-5.mol

Synonyms:107208-69-5;6-ACETYL-2-ISOPROPYLNAPHTHALENE;1-(6-propan-2-ylnaphthalen-2-yl)ethanone;1-(6-ISOPROPYLNAPHTHALEN-2-YL)ETHANONE;1-[6-(Propan-2-yl)naphthalen-2-yl]ethan-1-one;SCHEMBL10457062;DTXSID70549350;1-(6-isopropyl-2-naphthyl) ethanone;J-001730

Chemical Property of 6-Acetyl-2-isopropylnaphthalene

Chemical Property:

• PSA: 17.07000
• LogP: 4.16580
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 212.120115130
• Heavy Atom Count: 16
• Complexity: 256

Purity/Quality:

97% ^*data from raw suppliers

6-ACETYL-2-ISOPROPYLNAPHTHALENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C1=CC2=C(C=C1)C=C(C=C2)C(=O)C

Technology Process of 6-Acetyl-2-isopropylnaphthalene

There total 8 articles about 6-Acetyl-2-isopropylnaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

2,6-diisopropylnaphthalene (24157-81-1) → 2,6-diisopropenylnaphthalene + 1-(6-(1-methylethyl)naphthalen-2-yl)ethanone (107208-69-5) + 2-acetyl-6-isopropenylnaphthalene (1158403-07-6) + 2,6-diacetylnaphthalene (52387-51-6) + 2-isopropenyl-6-isopropyl-naphthalene

Guidance literature:

2,6-diisopropylnaphthalene; With N-hydroxyphthalimide; 2,2'-azobis(isobutyronitrile); oxygen; In acetonitrile; at 75 ℃; for 3h;

With cobalt(II) diacetate tetrahydrate; In acetonitrile; at 100 ℃; for 1h; Further stages; Inert atmosphere;

DOI:10.1016/j.tet.2009.03.013

Reference yield:

2,6-diisopropylnaphthalene (24157-81-1) → 1-(6-(1-methylethyl)naphthalen-2-yl)ethanone (107208-69-5) + 2,6-Naphthalenedicarboxylic acid (1141-38-4) + 2,6-diacetylnaphthalene (52387-51-6)

Guidance literature:

With oxygen; acetic acid; potassium bromide; at 189.84 ℃; for 12h; under 12751.3 Torr;

DOI:10.1016/j.apcata.2013.02.013

Reference yield:

2,6-diisopropylnaphthalene (24157-81-1) → 1-(6-(1-methylethyl)naphthalen-2-yl)ethanone (107208-69-5) + 2,6-Naphthalenedicarboxylic acid (1141-38-4) + 6-acetyl-2-naphthoic acid (33627-01-9) + 2,6-diacetylnaphthalene (52387-51-6)

Guidance literature:

With oxygen; acetic acid; potassium bromide; at 189.84 ℃; for 12h; under 12751.3 Torr; Reagent/catalyst;

DOI:10.1016/j.apcata.2013.02.013

upstream raw materials:

2,6-diisopropylnaphthalene

Downstream raw materials:

1-(6-hydroxy-2-naphthyl)ethan-1-one