1,1'-dibenzyl 2,2'-dimethyl (2S,2'S,3aR,3a'R,8aS,8a'S)-6,6'-dichloro-3a,3a'-bis((triethylsilyl)oxy)-3,3',3a,3a',8,8',8a,8a'-octahydro-5,5'-bipyrrolo[2,3-b]indole-1,1',2,2'(2H,2'H)-tetracarboxylate

Base Information

Chemical Name:1,1'-dibenzyl 2,2'-dimethyl (2S,2'S,3aR,3a'R,8aS,8a'S)-6,6'-dichloro-3a,3a'-bis((triethylsilyl)oxy)-3,3',3a,3a',8,8',8a,8a'-octahydro-5,5'-bipyrrolo[2,3-b]indole-1,1',2,2'(2H,2'H)-tetracarboxylate
CAS No.:1248759-45-6
Molecular Formula:C₅₂H₆₄Cl₂N₄O₁₀Si₂
Molecular Weight:1032.18
Hs Code.:

1,1'-dibenzyl 2,2'-dimethyl (2S,2'S,3aR,3a'R,8aS,8a'S)-6,6'-dichloro-3a,3a'-bis((triethylsilyl)oxy)-3,3',3a,3a',8,8',8a,8a'-octahydro-5,5'-bipyrrolo[2,3-b]indole-1,1',2,2'(2H,2'H)-tetracarboxylate

Synonyms:1,1'-dibenzyl 2,2'-dimethyl (2S,2'S,3aR,3a'R,8aS,8a'S)-6,6'-dichloro-3a,3a'-bis((triethylsilyl)oxy)-3,3',3a,3a',8,8',8a,8a'-octahydro-5,5'-bipyrrolo[2,3-b]indole-1,1',2,2'(2H,2'H)-tetracarboxylate

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Chemical Property of 1,1'-dibenzyl 2,2'-dimethyl (2S,2'S,3aR,3a'R,8aS,8a'S)-6,6'-dichloro-3a,3a'-bis((triethylsilyl)oxy)-3,3',3a,3a',8,8',8a,8a'-octahydro-5,5'-bipyrrolo[2,3-b]indole-1,1',2,2'(2H,2'H)-tetracarboxylate

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Technology Process of 1,1'-dibenzyl 2,2'-dimethyl (2S,2'S,3aR,3a'R,8aS,8a'S)-6,6'-dichloro-3a,3a'-bis((triethylsilyl)oxy)-3,3',3a,3a',8,8',8a,8a'-octahydro-5,5'-bipyrrolo[2,3-b]indole-1,1',2,2'(2H,2'H)-tetracarboxylate

There total 2 articles about 1,1'-dibenzyl 2,2'-dimethyl (2S,2'S,3aR,3a'R,8aS,8a'S)-6,6'-dichloro-3a,3a'-bis((triethylsilyl)oxy)-3,3',3a,3a',8,8',8a,8a'-octahydro-5,5'-bipyrrolo[2,3-b]indole-1,1',2,2'(2H,2'H)-tetracarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 1248759-39-8
1-benzyl 2-methyl (2S,3aR,8aS)-6-chloro-5-iodo-3a-((triethylsilyl)oxy)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1,2(2H)-dicarboxylate

: 1248759-42-3
1-benzyl 2-methyl (2S,3aR,8aS)-6-chloro-3a-((triethylsilyl)oxy)-5-(trimethylstannyl)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1,2(2H)-dicarboxylate

: 1248759-45-6
1,1'-dibenzyl 2,2'-dimethyl (2S,2'S,3aR,3a'R,8aS,8a'S)-6,6'-dichloro-3a,3a'-bis((triethylsilyl)oxy)-3,3',3a,3a',8,8',8a,8a'-octahydro-5,5'-bipyrrolo[2,3-b]indole-1,1',2,2'(2H,2'H)-tetracarboxylate

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; copper(l) iodide; triphenyl-arsane; In N,N-dimethyl-formamide; at 100 ℃; Microwave irradiation;
DOI:10.1002/anie.201002880

Reference yield: 36.0%

: 1248759-39-8
1-benzyl 2-methyl (2S,3aR,8aS)-6-chloro-5-iodo-3a-((triethylsilyl)oxy)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1,2(2H)-dicarboxylate

: 1301725-50-7
1-benzyl 2-methyl (2S,3aR,8aS)-6-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-3a-((triethylsilyl)oxy)-3,3a,8,8a-tetrahydropyrrolo[2,3-b]indole-1,2(2H)-dicarboxylate

: 1248759-45-6
1,1'-dibenzyl 2,2'-dimethyl (2S,2'S,3aR,3a'R,8aS,8a'S)-6,6'-dichloro-3a,3a'-bis((triethylsilyl)oxy)-3,3',3a,3a',8,8',8a,8a'-octahydro-5,5'-bipyrrolo[2,3-b]indole-1,1',2,2'(2H,2'H)-tetracarboxylate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydroxide; In water; toluene; at 50 ℃;
DOI:10.1002/chem.201003216