Iodine monochloride

Base Information

• Chemical Name: Iodine monochloride
• CAS No.: 7790-99-0
• Molecular Formula: ClI
• Molecular Weight: 162.358
• Hs Code.: 3822 00 00
• European Community (EC) Number: 232-236-7
• UN Number: 1792
• UNII: 0SMG5NLU45
• DSSTox Substance ID: DTXSID1064879
• Nikkaji Number: J95.175G
• Wikipedia: Iodine monochloride
• Wikidata: Q414607
• Mol file: 7790-99-0.mol

Synonyms:iodine monochloride;iodine monochloride, 125I-labeled

Chemical Property of Iodine monochloride

Chemical Property:

• Appearance/Colour: dark red or brown solid and/or liquid
• Vapor Pressure: 31.4mmHg at 25°C
• Melting Point: 25-27°C
• Refractive Index: 1.591
• Boiling Point: 97.4 °C at 760 mmHg
• Flash Point: 96-98°C
• PSA: 0.00000
• Density: 2.763 g/cm³
• LogP: 1.57520
• Storage Temp.: 2-8°C
• Sensitive.: Moisture Sensitive
• Solubility.: acetic acid: soluble(lit.)
• Water Solubility.: decomposes
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 161.87333
• Heavy Atom Count: 2
• Complexity: 2
• Transport DOT Label: Corrosive

Purity/Quality:

99% ^*data from raw suppliers

Iodine Monochloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34-42-35-10-40-67-37
• Safety Statements: 26-36/37/39-45-23

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Halogenated Aliphatics, Saturated
• Canonical SMILES: ClI
• Physical properties: Colorless gas; mold-like pungent odor; melting point 6.45°C; sublimes at4.77°C; supercools to a colorless liquid that boils at 4.5°C; liquid density2.8g/mL at 6°C; soluble in water.
• Uses: Iodine monochloride is used to estimate theiodine values of fats and oils and as a topicalanti-infective (Merck 1996). For determination of iodine absorption number of fatsIodine monochloride is used as a catalyst in organic synthesis. It is the source of electrophilic iodine in the synthesis of certain aromatic iodides. It is used to determine the iodine value of a substance. In Wijs' solution (iodine monochloride in glacial acetic acid), used to determine iodine values of fats and oils.

Technology Process of Iodine monochloride

There total 114 articles about Iodine monochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.6%

sodium chlorate + iodine (7553-56-2,12190-71-5,8031-47-8) → Iodine monochloride (7790-99-0)

Guidance literature:

With hydrogenchloride; sodium chloride; In water; at 25 - 27 ℃; for 19h;

Reference yield: 85.0%

iodine (7553-56-2,12190-71-5,8031-47-8) + chlorine (7782-50-5) → Iodine monochloride (7790-99-0) + iodine trichloride (865-44-1)

Guidance literature:

In neat (no solvent); passing dry chlorine over dry iodine;; distillation in stream of chlorine at 100-101.5°C;;

DOI:10.1021/ja01344a021

Reference yield:

antimonypentachloride (7647-18-9) → SbCl5*I + antimony(III) chloride (10025-91-9) + Iodine monochloride (7790-99-0) + antimony triiodide (7790-44-5) + iodine trichloride (865-44-1)

Guidance literature:

byproducts: antimony(V) chloroiodide; room temp.;

upstream raw materials:

dichloroiodomethane

water

hydrogenchloride

cyanogen iodide

Downstream raw materials:

chloroethane

2,5-Dichloro-1,4-benzoquinone

4-tolyl iodide

hexachlorobenzene

Refernces

• 1、 Drobits, Janet C.,Lester, Marsha I.. "Near threshold photofragmentation dynamics of ICl-Ne A state van der Waals complexes". . p. 120 - 128. Retrieved 1988.
• 2、 Lilenfeld, H. V.,Whitefield, P. D.,Bradburn, G. R.. "I(2P1/2) Deactivation by ICl and Cl2". . p. 6158 - 6162. Retrieved 1984.
• 3、 -. "Preparation method of hexafluorobutadiene". Paragraph 0039; 0045-0046; 0052; 0057-0059; 0064; 0069-0071. . Retrieved 2021/01/29.
• 4、 -. "Tricyclic pyridine derivatives, medicaments containing such compounds, their use and process for their preparation". Paragraph 1083; 1084; 1085; 1086. . Retrieved 2013/03/26.