6,6′-((1E,1′E)-((methylenebis(4,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(2-methoxyphenol)

Base Information

• Chemical Name: 6,6′-((1E,1′E)-((methylenebis(4,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(2-methoxyphenol)
• CAS No.: 16927-65-4
• Molecular Formula: C₂₉H₂₆N₂O₄
• Molecular Weight: 466.536
• Mol file: 16927-65-4.mol

Synonyms:6,6′-((1E,1′E)-((methylenebis(4,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(2-methoxyphenol)

Chemical Property of 6,6′-((1E,1′E)-((methylenebis(4,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(2-methoxyphenol)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6,6′-((1E,1′E)-((methylenebis(4,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(2-methoxyphenol)

There total 2 articles about 6,6′-((1E,1′E)-((methylenebis(4,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(2-methoxyphenol) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-methoxy-2-hydroxybenzaldehyde (148-53-8) + 4,4'-diamino diphenyl methane (101-77-9) → 6,6′-((1E,1′E)-((methylenebis(4,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(2-methoxyphenol) (16927-65-4)

Guidance literature:

In methanol; at 20 ℃; for 12h;

DOI:10.1016/j.inoche.2011.05.015

Reference yield:

→ 6,6′-((1E,1′E)-((methylenebis(4,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(2-methoxyphenol) (16927-65-4)

Guidance literature:

4,4'-Diamino-diphenylmethan, 2-Hydroxy-3-methoxybenzaldehyd;

DOI:10.1021/je60035a033

Reference yield: 28.0%

[Cu2(OAc)4(H2O)2] (879089-16-4,155065-88-6) + 6,6′-((1E,1′E)-((methylenebis(4,1-phenylene))bis(azanylylidene))bis(methanylylidene))bis(2-methoxyphenol) (16927-65-4) → CH2(C6H4NCHC6H3(OCH3)O)2(2-)*Cu(2+)=(CH2(C6H4NCHC6H3(O)OCH3)2)Cu (17668-29-0)

Guidance literature:

In methanol; chloroform; soln. of Cu salt in MeOH added to soln. of ligand in CHCl3/MeOH (1/1); filtered, filtrate allowed to evap. in air, ppt. filtered off, washed with EtOH; elem. anal.;

DOI:10.1039/b403181d

upstream raw materials:

3-methoxy-2-hydroxybenzaldehyde

4,4'-diamino diphenyl methane

Downstream raw materials:

CH₂(C₆H₄NCHC₆H₃(OCH₃)O)2^(2-)*Cu⁽²⁺⁾=(CH₂(C₆H₄NCHC₆H₃(O)OCH₃)2)Cu