RU(Oac)2[(R)-tolbinap]

Base Information

Chemical Name:RU(Oac)2[(R)-tolbinap]
CAS No.:106681-15-6
Molecular Formula:C₅₂H₄₆O₄P₂Ru
Molecular Weight:897.952
Hs Code.:
European Community (EC) Number:634-602-5
Mol file:106681-15-6.mol

Synonyms:106681-15-6;116128-29-1;RU(OAC)2[(R)-TOLBINAP];(R)-Ru(OAc)2(T-BINAP);(S)-Ru(OAc)2(T-BINAP);RU(OAC)2[(S)-TOLBINAP];acetic acid;[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;ruthenium;Diacetato[(R)-(+)-2,2/'-bis(di-p-tolylphosphino)-1,1/'-binaphthyl]ruthenium(II);Diacetato[(S)-(-)-2,2/'-bis(di-p-tolylphosphino)-1,1/'-binaphthyl]ruthenium(II);Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap];AKOS015908623;SC10146;E81026;(1-{2-[bis(4-methylphenyl)phosphanyl]naphthalen-1-yl}naphthalen-2-yl)bis(4-methylphenyl)phosphane (acetyloxy)ruthenio acetate;Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II), Ru(OAc)2[(R)-tolbinap]

Suppliers and Price of RU(Oac)2[(R)-tolbinap]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
Ru(OAc)2[(S)-tolbinap]
1g
$ 160.00

TCI Chemical
Ru(OAc)2[(S)-tolbinap]
200mg
$ 50.00

Strem Chemicals
Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap]
250mg
$ 53.00

Strem Chemicals
Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap]
5g
$ 379.00

Strem Chemicals
Diacetato[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-tolbinap]
1g
$ 158.00

Sigma-Aldrich
(S)-Ru(OAc)2(T-BINAP)
500mg
$ 98.20

Sigma-Aldrich
(S)-Ru(OAc)2(T-BINAP)
100mg
$ 24.90

Chem-Impex
Ru(OAc)2[(S)-tolbinap]
1G
$ 189.86

Chem-Impex
Ru(OAc)2[(S)-tolbinap]
200MG
$ 52.42

Chemenu
Diacetato[(S)-(-)-2,2''-bis(di-p-tolylphosphino)-1,1''-binaphthyl]ruthenium(II),Ru(OAc)2[(S)-tolbinap] 95%
1g
$ 280.00

Total 17 raw suppliers

Chemical Property of RU(Oac)2[(R)-tolbinap]

Chemical Property:

Melting Point:>100°C
PSA：79.78000
LogP:10.43760
Storage Temp.:2-8°C
Sensitive.:air sensitive
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:7
Exact Mass:900.207124
Heavy Atom Count:59
Complexity:975

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ru(OAc)2[(S)-tolbinap] ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.CC(=O)O.CC(=O)O.[Ru]
Uses Takasago Ligands and Complexes for Asymmetric Reactions

Technology Process of RU(Oac)2[(R)-tolbinap]

There total 4 articles about RU(Oac)2[(R)-tolbinap] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 153305-67-0,100165-88-6,99646-28-3
(+)-(R)-2,2'bis(di-para-tolylphosphanyl)-1,1'binaphthyl

: dichloro(1,5-cyclooctadiene)ruthenium(II)

: 112065-78-8,114818-53-0,106681-15-6,116128-29-1
diacetato[(S)-(-)-2,2′-bis(di-p-tolylphosphino)-1,1′-binaphthyl]ruthenium(II)

Guidance literature:: With sodium acetate; triethylamine; In toluene; tert-butyl alcohol; react. of (RuCl2(cod))2 with (S)-BINAP-derivative and N(C2H5)3 in toluene, then addn. of NaO2CCH3;;

Reference yield:

: 153305-67-0,100165-88-6,99646-28-3
(R)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl

: dichloro(1,5-cyclooctadiene)ruthenium(II)

: 112065-78-8,114818-53-0,106681-15-6,116128-29-1
diacetato[(R)-(+)-2,2-bis(di-p-tolylphosphono)-1,1′?binaphthyl]ruthenium(II)

Guidance literature:: With sodium acetate; triethylamine; In toluene; tert-butyl alcohol; react. of (RuCl2(cod))2 with (R)-BINAP-derivative and N(C2H5)3 in toluene, then addn. of sodium acetate;;