[Fe((η5-C5H4)-C(CH3)=N-C6H4Cl-4)2]

Base Information

Chemical Name:[Fe((η5-C5H4)-C(CH3)=N-C6H4Cl-4)2]
CAS No.:182273-76-3
Molecular Formula:C₂₆H₂₂Cl₂FeN₂
Molecular Weight:489.227
Hs Code.:

Synonyms:[Fe((η5-C5H4)-C(CH3)=N-C6H4Cl-4)2]

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Chemical Property of [Fe((η5-C5H4)-C(CH3)=N-C6H4Cl-4)2]

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Technology Process of [Fe((η5-C5H4)-C(CH3)=N-C6H4Cl-4)2]

There total 1 articles about [Fe((η5-C5H4)-C(CH3)=N-C6H4Cl-4)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 1273-94-5
1,1'-diacetylferrocene

: 106-47-8
4-chloro-aniline

: 182273-76-3
[Fe((η5-C5H4)-C(CH3)=N-C6H4Cl-4)2]

Guidance literature:: titanium tetrachloride; In toluene; (Ar); 4 equiv. of aniline ligand added to diacetylferrocene and TiCl4 intoluene; refluxed for 6-8 h; washed with water 3 times; organic phase dried over anhydrous Na2SO4; filtered; solvent removed under reduced pressure; purified by flash chromy. (silica gel, EtOAc/hexane 1:5); elem. anal.;
DOI:10.1016/j.poly.2006.09.093

Reference yield: 89.0%

: 16853-85-3
lithium aluminium tetrahydride

: 182273-76-3
[Fe((η5-C5H4)-C(CH3)=N-C6H4Cl-4)2]

: 936024-91-8
[Fe((η5-C5H4)-CH(CH3)NH-C6H4Cl-4)2]

Guidance literature:: With AlCl₃; In tetrahydrofuran; (Ar); AlCl3 soln. added to stirred THF soln. of Fe-compound; stirred for30 min at room temp.; LiAlH4 added in 1 portion; refluxed for 1 h; solv ent evapd. under reduced pressure; CH2Cl2 added; stirred for 1 h; extraction phase dried over Na2SO4; filtered; solvent removed; purified by column chromy. (silica gel, EtOAc/hexane 1:3); elem. anal.;
DOI:10.1016/j.poly.2006.09.093

Reference yield: 10.0%

: lithium tetrachloropalladate

: 182273-76-3
[Fe((η5-C5H4)-C(CH3)=N-C6H4Cl-4)2]

: 603-35-0
triphenylphosphine

: 185226-37-3,185065-99-0
[Fe(C₅H₃C(CH₃)N(C₆H₄Cl)PdCl(P(C₆H₅)3))2]

: 185065-99-0,185226-37-3
[Fe(C₅H₃C(CH₃)N(C₆H₄Cl)PdCl(P(C₆H₅)3))2]

Guidance literature:: With sodium acetate; In methanol; dichloromethane; stirring the palladate and ferrocenylimine in the presence of anhydrous NaOAc in MeOH/CH2Cl2 at room temp. for ca. 20 h, evapn. (vac.), washing (MeOH), addn. of PPh3 in CH2Cl2, stirring (room temp., 0.5 h); chromy. (SiO2; CH2Cl2), evapn., recrystn. (CH2Cl2/petroleum ether); elem. anal.;
DOI:10.1016/0277-5387(96)00101-5