(2R,3R,4R,5S,6R)-5,7-bis-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6-trimethylheptanal

Base Information

• Chemical Name: (2R,3R,4R,5S,6R)-5,7-bis-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6-trimethylheptanal
• CAS No.: 152328-93-3
• Molecular Formula: C₃₀H₅₆O₅Si₂
• Molecular Weight: 552.943

Synonyms:(2R,3R,4R,5S,6R)-5,7-bis-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6-trimethylheptanal

Chemical Property of (2R,3R,4R,5S,6R)-5,7-bis-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6-trimethylheptanal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2R,3R,4R,5S,6R)-5,7-bis-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6-trimethylheptanal

There total 2 articles about (2R,3R,4R,5S,6R)-5,7-bis-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6-trimethylheptanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

(2R,3S,4R,5S,6S)-1,3-di-[(tert-butyldimethylsilyl)oxy]-5-(4-methoxybenzyl)oxy-2,4,6-trimethyloct-7-ene → (2R,3R,4R,5S,6R)-5,7-bis-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6-trimethylheptanal (152328-93-3)

Guidance literature:

(2R,3S,4R,5S,6S)-1,3-di-[(tert-butyldimethylsilyl)oxy]-5-(4-methoxybenzyl)oxy-2,4,6-trimethyloct-7-ene; With ozone; In methanol; dichloromethane; at -78 ℃; for 0.0833333h;

With dimethylsulfide; In methanol; dichloromethane; at 20 ℃; for 72h; Further stages.;

DOI:10.1021/jo0104429

Reference yield:

(2S,2S,4R,5S,6R)-5,7-bis-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4,6-trimethyl-heptan-1-ol → (2R,3R,4R,5S,6R)-5,7-bis-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6-trimethylheptanal (152328-93-3)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; at 0 - 20 ℃; for 4.5h;

DOI:10.1002/anie.200701065

Reference yield: 62.0%

(E)-(4S,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-4,6-dimethyl-7-oxo-non-2-enoic acid (2S,3R,4S,6R,8S,9S)-8-[(R)-2-(tert-butyl-dimethyl-silanyloxy)-propyl]-2-((E)-(R)-3-ethyl-5-iodo-pent-4-enyl)-3,9-dimethyl-1,7-dioxa-spiro[5.5]undec-4-yl ester (203063-87-0) + (2R,3R,4R,5S,6R)-5,7-bis-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6-trimethylheptanal (152328-93-3) → C74H137IO12Si4 (359796-02-4)

Guidance literature:

With titanium tetrachloride; N-ethyl-N,N-diisopropylamine; In dichloromethane; at -78 - -30 ℃;

DOI:10.1021/jo0104429

Downstream raw materials:

C₇₄H₁₃₇IO₁₂Si₄

(2E,4E)-(6S,7S,8R,9S,10R)-9,11-bis-(tert-butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-6,8,10-trimethyl-undeca-2,4-dienoic acid methyl ester

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 152328-93-3 (2R,3R,4R,5S,6R)-5,7-bis-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4,6-trimethylheptanal

Send

Send

Metric Ton KG G Pound L ML

Send

Send