(R)-(+)-4,4,5,5-tetramethyl-2-(4-methyl-2-phenylpentyl)-1,3,2-dioxaborolane

Base Information

Chemical Name:(R)-(+)-4,4,5,5-tetramethyl-2-(4-methyl-2-phenylpentyl)-1,3,2-dioxaborolane
CAS No.:1325729-43-8
Molecular Formula:C₁₈H₂₉BO₂
Molecular Weight:288.238
Hs Code.:

Synonyms:(R)-(+)-4,4,5,5-tetramethyl-2-(4-methyl-2-phenylpentyl)-1,3,2-dioxaborolane

Suppliers and Price of (R)-(+)-4,4,5,5-tetramethyl-2-(4-methyl-2-phenylpentyl)-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (R)-(+)-4,4,5,5-tetramethyl-2-(4-methyl-2-phenylpentyl)-1,3,2-dioxaborolane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (R)-(+)-4,4,5,5-tetramethyl-2-(4-methyl-2-phenylpentyl)-1,3,2-dioxaborolane

There total 2 articles about (R)-(+)-4,4,5,5-tetramethyl-2-(4-methyl-2-phenylpentyl)-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 38212-14-5
1-isobutylvinylbenzene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1325729-43-8
(R)-(+)-4,4,5,5-tetramethyl-2-(4-methyl-2-phenylpentyl)-1,3,2-dioxaborolane

: (S)-4,4,5,5-tetramethyl-2-(4-methyl-2-phenylpentyl)-1,3,2-dioxaborolane

Guidance literature:: With C₂₉H₃₃Cl₂FeN₃O; sodium triethylborohydride; In tetrahydrofuran; diethyl ether; at 0 ℃; for 1h; Overall yield = 69 %; Overall yield = 0.0987 mg; enantioselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/ol503282r

Reference yield:

: 38212-14-5
1-isobutylvinylbenzene

: 73183-34-3
bis(pinacol)diborane

: 1325729-43-8
(R)-(+)-4,4,5,5-tetramethyl-2-(4-methyl-2-phenylpentyl)-1,3,2-dioxaborolane

: (S)-4,4,5,5-tetramethyl-2-(4-methyl-2-phenylpentyl)-1,3,2-dioxaborolane

Guidance literature:: bis(pinacol)diborane; With C₃₄H₂₈N₂O₃S; copper(l) chloride; sodium t-butanolate; In tetrahydrofuran; for 0.5h; Inert atmosphere;

1-isobutylvinylbenzene; With methanol; In tetrahydrofuran; at -15 ℃; for 48h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/anie.201102398