2-azi-1-(tert-butyldimethylsilyloxy)-10-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)decane

Base Information

Chemical Name:2-azi-1-(tert-butyldimethylsilyloxy)-10-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)decane
CAS No.:186091-13-4
Molecular Formula:C₅₀H₆₀N₂O₁₁Si
Molecular Weight:893.119
Hs Code.:

Synonyms:2-azi-1-(tert-butyldimethylsilyloxy)-10-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)decane

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Chemical Property of 2-azi-1-(tert-butyldimethylsilyloxy)-10-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)decane

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Technology Process of 2-azi-1-(tert-butyldimethylsilyloxy)-10-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)decane

There total 4 articles about 2-azi-1-(tert-butyldimethylsilyloxy)-10-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 186091-13-4
2-azi-1-(tert-butyldimethylsilyloxy)-10-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)decane

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / imidazole / dimethylformamide / 3 h / Ambient temperature

2: 93 percent / NaOMe / methanol / 12 h / Ambient temperature

3: 1.) tetramethylurea, silver trifluoromethanesulfonate, 4A molecular sieves / 1.) CH₂Cl₂, rt, 1 h, 2.) CH₂Cl₂, -20 deg C, 4 h

With 1H-imidazole; 4 A molecular sieve; sodium methylate; silver trifluoromethanesulfonate; tetramethylurea; In methanol; N,N-dimethyl-formamide;
DOI:10.1016/S0008-6215(96)00207-8

Reference yield:

: Acetic acid 8-(3-hydroxymethyl-3H-diazirin-3-yl)-octyl ester

: 186091-13-4
2-azi-1-(tert-butyldimethylsilyloxy)-10-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)decane

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / imidazole / dimethylformamide / 3 h / Ambient temperature

2: 93 percent / NaOMe / methanol / 12 h / Ambient temperature

3: 1.) tetramethylurea, silver trifluoromethanesulfonate, 4A molecular sieves / 1.) CH₂Cl₂, rt, 1 h, 2.) CH₂Cl₂, -20 deg C, 4 h

With 1H-imidazole; 4 A molecular sieve; sodium methylate; silver trifluoromethanesulfonate; tetramethylurea; In methanol; N,N-dimethyl-formamide;
DOI:10.1016/S0008-6215(96)00207-8

Reference yield:

: 186091-11-2
Acetic acid 8-[3-(tert-butyl-dimethyl-silanyloxymethyl)-3H-diazirin-3-yl]-octyl ester

: 186091-13-4
2-azi-1-(tert-butyldimethylsilyloxy)-10-(2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyloxy)decane

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / NaOMe / methanol / 12 h / Ambient temperature

2: 1.) tetramethylurea, silver trifluoromethanesulfonate, 4A molecular sieves / 1.) CH₂Cl₂, rt, 1 h, 2.) CH₂Cl₂, -20 deg C, 4 h

With 4 A molecular sieve; sodium methylate; silver trifluoromethanesulfonate; tetramethylurea; In methanol;
DOI:10.1016/S0008-6215(96)00207-8