7-(tert-butyldimethylsilyloxy)-8-methylnaphthalen-2-yl 4-(4-dodecylbenzoyloxy)benzoate

Base Information

• Chemical Name: 7-(tert-butyldimethylsilyloxy)-8-methylnaphthalen-2-yl 4-(4-dodecylbenzoyloxy)benzoate
• CAS No.: 1250377-54-8
• Molecular Formula: C₄₃H₅₆O₅Si
• Molecular Weight: 681
• Mol file: 1250377-54-8.mol

Synonyms:7-(tert-butyldimethylsilyloxy)-8-methylnaphthalen-2-yl 4-(4-dodecylbenzoyloxy)benzoate

Chemical Property of 7-(tert-butyldimethylsilyloxy)-8-methylnaphthalen-2-yl 4-(4-dodecylbenzoyloxy)benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7-(tert-butyldimethylsilyloxy)-8-methylnaphthalen-2-yl 4-(4-dodecylbenzoyloxy)benzoate

There total 4 articles about 7-(tert-butyldimethylsilyloxy)-8-methylnaphthalen-2-yl 4-(4-dodecylbenzoyloxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

4-(4-n-dodecylbenzoyloxy)benzoic acid + C17H24O2Si → 7-(tert-butyldimethylsilyloxy)-8-methylnaphthalen-2-yl 4-(4-dodecylbenzoyloxy)benzoate (1250377-54-8)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c0jm00375a

Reference yield:

4-dodecylbenzoic acid (21021-55-6) → 7-(tert-butyldimethylsilyloxy)-8-methylnaphthalen-2-yl 4-(4-dodecylbenzoyloxy)benzoate (1250377-54-8)

Guidance literature:

Multi-step reaction with 3 steps

1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 12 h / 20 °C / Inert atmosphere

2: Jones reagent / acetone

3: dmap; dicyclohexyl-carbodiimide / dichloromethane / 24 h / 20 °C / Inert atmosphere

With dmap; Jones reagent; dicyclohexyl-carbodiimide; In dichloromethane; acetone;

DOI:10.1039/c0jm00375a

Reference yield:

C26H34O3 (1250377-57-1) → 7-(tert-butyldimethylsilyloxy)-8-methylnaphthalen-2-yl 4-(4-dodecylbenzoyloxy)benzoate (1250377-54-8)

Guidance literature:

Multi-step reaction with 2 steps

1: Jones reagent / acetone

2: dmap; dicyclohexyl-carbodiimide / dichloromethane / 24 h / 20 °C / Inert atmosphere

With dmap; Jones reagent; dicyclohexyl-carbodiimide; In dichloromethane; acetone;

DOI:10.1039/c0jm00375a

upstream raw materials:

C₂₆H₃₄O₃

4-dodecylbenzoic acid

4-hydroxy-benzaldehyde

Downstream raw materials:

7-hydroxy-8-methylnaphthalen-2-yl 4-(4-dodecylbenzoyloxy)benzoate

4-[(7-(4-(4-dodecylbenzoyloxy)benzoyloxy)-1-methylnaphthalen-2-yloxy)carbonyl]phenyl 5-dodecylthiophene-2-carboxylate